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GC/MS calibration data for TCLP method, Oct 2001

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Calibration table and chromatographic data for GC/MS analysis using the TCLP method, recorded on October 3-4, 2001.

NYC-WTC_000087722–000087730

Folder label: “GC/MS Scan 9/21/01

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NYC 9/11 Public Portal Document LiiDrary searcn Compound Report Data File C;\HPCHEM\1\DATA\OCT03 01\LB .D Vial: 2 Acq On 3 Oct 2001 1:37 pm Operator: 209 GALOS Sample * 9/21 Inst ; GC/MS 209 Mise Multiplr: 1.00 MS Integration Params; LSCINT.P

Quant Method : C;\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 1,4-Dichlorobenzene-d4 Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 11.64 0.51 ug/1 68358 1,4-Dichlorobenzene-d4 11.78

Hit# of 5 ;ntative ID MW MolForm CAS# Qual

1 1,4-Dichl^obenzene-d4 150 C6C12D4 003855-82-1 53 2 Benzene-^2,3,4-d4-, 5,6-dichloro- 150 C6C12D4 002199-69-1 33 3 Benzaldehyde, 2-hydroxy-3-methoxy- 152 C8H8O3 000148-53-8 10 4 Vanillin 152 C8H8O3 000121-33-5 9 Abundance Scan 719 (11.642 min): LB.D (-) m/z 149.90 100.00% 1!i0

252 115 78 52 38 44 I I 11.40 11.60 11.80 12.00 . ................................. |hi|'I|i 4.^ m/z 151.90 . 64.31% ll/Z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #9593:1,4-Dichlorobenzene-d4 1!i0

5000 115 78 11.40 11.60 11.80 12.00 52 m/z 114.90 34.61% 35 TiZz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #9592: Benzene-1,2,3,4-d4-, 5,6-dichloro- liiO

115 11.40 11.60 11.80 12.00 5000 52 78 m/z 78.05 21.02%

87

Ti/z-> 30 35 I 40 50 ' I' ' ' ' I ' 60 70 I ' r ' ' ' I ‘ 80 90 100 110 120 130 A 140 150 160 Abundance #66892: Benzaldehyde, 2-hydroxy-3-methoxy- 1!12 11.40 11.60 11.80 12.00 m/z 52.00 . 14.41% 106 c 552 53 81

122 Tpr-r 136 I ' ' I ' ' ' ' I ' ' ' ’ I ' ' I' ' ' ' I ' ' ' ' I T T n/z~> 30 40 50 60 70 80 100 110 120 130 140 150 160 11.40 11.60 11.80 12.00

LB.D NP091101.M Fri Oct 05 14:20:21 2001 Page 2

NYC-WTC_000087729

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NYC-WTC_000087729Source: NYC Law Department, mirrored locally

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