GC/MS calibration data for TCLP method, Oct 2001

NYC 9/11 Public Portal Document uxjjidxy iiearcn compouna Report

Data File : C:\HPCHEM\1\DATA\OCT0301\LB.D Vial: 2 Acq On : 3 Oct 2001 1:37 pm Operator: 209 GALOS Sample : 9/21 Inst : GC/MS 209 Mise : Multiplr; 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Hexanone Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 6.47 0.48 ug/1 64562 1,4-Dichlorobenzene-d4 11.78

Hit# of 5 'entative ID MW MolForm CAS# Qual

1 2-Hexanone 100 C6H12O 000591-78-6 91 2 2-Hexa^ne, 4-hydroxy-5-methyl-3-pr 172 C10H20O2 061141-74-0 74 3 Oxiranfe,. 2-methyl-2-(1-methylethyl) 100 C6H12O 072221-03-5 72 4 2-HeXanone, 4-hydroxy-3-propyl- 158 C9H18O2 062338-17-4 72 ^bundance^C Scan 156 (6.473 min): LB.D (-) m/z 42.95 100.00% 4(3

58 5000

71 85 iro 6.20 6.40 6.60 6.80 I ' H I I I H I I I I ...... ... 11" " I" " 11" 111111| ■ ■ ■ 1111" I" ■ 111" ■ I ■ 1" 111..( m/z 58705 54.05% Ti/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #1556; 2-Hexanone 43

58 5000 6.20 6.40 6.^ 6.^ m/z 57700 17704% 27 71 85 iro I" " I' I" I'''' I' ‘ ‘ 11' 11''' I" " I'''' 1" '' I" '' I' " ' I" " I'' " I Tife-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 /\bundance #15807:2-Hexanone, 4-hydroxy-5-methyl-3-propyl- 4)3

' ' ' ' I ' ‘ ' I ' ' ' ' I ' ' ' ' I ' ' ' ' 6.20 6.40 6.60 6.80 5000 m/z 41700 14778% 58 27 72 I 85 100 ............. 'I' 'I'.... II'I'"' TiZz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 r\bundance #1530: Oxirane, 2-methyl-2-(1-methylethyl)- 4{3 6.20 6.40 6.60 6.80 58 m/z 84.95 17737%

L. 5000 71

30 -4- r+ Ar 66 'I.......... 85 100 ..... ............... . d,/ ■n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 6.20 6.40 6.60 6.80

LB.D NP091101.M Fri Oct 05 14:20:19 2001 Page 1

NYC-WTC_000087728