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GC/MS calibration table for TCLP analysis, Oct 18 2001

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Calibration data table for TCLP analysis using GC/MS standards processed on October 18, 2001.

NYC-WTC_000088491–000088503

Folder label: “GC/MS Scan 9/26/01

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File ; C:\HPCHEM\1\DATA\OCT1801\LB.D Vial: 2 Acq On : 18 Oct 2001 5:09 pm Operator: 209 GALOS Sample : lab blk 10/15 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 6 1,4-Dichlorobenzene-d4 Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 11.63 0.51 ug/1 49498 1,4-Dichlorobenzene-d4 11.77 Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 1,4-Dichl^obenzene-d4 150 C6C12D4 003855-82-1 53 2 Benzene-/; 2,3,4-d4-, 5,6-dichloro- 150 C6C12D4 002199-69-1 16 3 Benzal [ehyde, 2-hydroxy-3-methoxy- 152 C8H8O3 000148-53-8 10 4 Vanil]/ .n 152 C8H8O3' 000121-33-5 9 Abundance Scan 718 (11.629 min); LB.D (-) m/z 150.00 100.00% 1$0 (1 5000 115 78 52 11.20 11.40 11.60 11.80 12.00 ,.rrrrJfrTTTTi+-*r^^ I “raTz^TsTTgO 66.60% nfe-> 30 40 50 60 70 80 90 100 120 110 130 140 150 160 <\bundance #9593:1,4-Dichlorobenzene-d4 1!i0

5000 115 ' ' I ' 78 11.20 11.40 11.60 11.80 12.00 52 m/z 115.00 . 38.67% 35 1,1..... . ■nlz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #9592: Benzene-1,2,3,4-84-, 5,6-dichloro- 150 T 115 11.20 11.40 11.60 11.80 12.00 5000- 52 78 m/z 78.05 . 22.85%

35 87 I I ' ' I ' ' ' ' I ' ' ’ ' I tVz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #66892: Benzaldehyde, 2-hydroxy-3-methoxy- 152 11.20 11.40 11.60 11.80 12.00 “Wz 52.00 15.82% 106 5000- 53 81

92 122 ' ' ' I I ' ' ‘ I ' 136 I ■ I I > I ' I ' '' • 1 •n/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 11.20 11.40 11.60 11.80 12.00

LB.D NP091101.M Fri Oct 19 10:25:56 2001 Page 6

NYC-WTC_000088502

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NYC-WTC_000088502Source: NYC Law Department, mirrored locally

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