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GC/MS calibration data for TCLP method, Oct 2001

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Calibration table and chromatographic data for the TCLP method using GC/MS instrument 209, dated October 3, 2001.

NYC-WTC_000087496–000087516

Folder label: “GC/MS Scan 9/20/01

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NYC 9/11 Public Portal Document Library Search Compound Report Data File ; C:\HPCHEM\1\DATA\OCT0201\LB.D Vial; 2 Acq On : 2 Oct 2001 3:06 pm Operator; 209 GALOS Sample ; 9/20 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params; LSCINT.P

Quant Method ; C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library : C;\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Hexanone Concentration Rank 8 R.T. EstConc Area Relative to ISTD R.T. 6.49 0.83 ug/1 107024 1,4-Dichlorobenzene-d4 11.78 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2-Hexan^e 100 C6H12O 000591-78-6 91 2 Methyy Isobutyl Ketone 100 C6H12O 000108-10-1 58 3 2-H^ :anone, 4-hydroxy-3-propyl- 158 C9H18O2 062338-17-4 56 4 Oxy ane, 2-methyl-2-(1-methylethyl) 100 C6H12O 072221-03-5 50 ^bundatJefe Scan 158 (6.488 min): LB.D (-) m/z 42.95 100.00% 43

58 5000 ..................... 71 85 100 6.20 6.40 6.60 6.80 ................. '! I I ' ' ' ' I ' ‘ ' I ' ' ' ‘ I ' m/z 58.05 53.87% 20 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #1556: 2-Hexanone 43

58 5000 __6,20__a40__6J0__6J0_^ "m/z 41.05 16.10% 27 71 85 100 I, , ,1, |I -t-rry. mZz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #63354: Methyl Isobutyl Ketone 43

6,20 6,40 6.60 6,80 5000 "m/z SYT^O 14.47% 58 I , 85 100 ............. 1,1, 1. 67 I I m/z-> 20 30 40 50I 60 70 80 90 100 110 120 130 140 Abundance #11968: 2-Hexanone, 4-hydroxy-3-propyl- ...................... 43 6.20 6,40 6,60 6,80 m/z 100.00 10.23% 58 29 A 5000

'I''''I''' 'II ,1 7 T ' I''' I'l'''' I'''' 1'''' I'''' I'''' I'''' I'''' I' 140 ■nfe-> 20 30 40 50 60 70 80 90 100 110 120 130 140 6.20 6.40 6.60 6.80

LB.D NP091101.M Wed Oct 03 10:09:46 2001 Page 2

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