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GC/MS calibration data for TCLP method, Oct 2001

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Calibration table and chromatographic data for the TCLP method using GC/MS instrument 209, dated October 3, 2001.

NYC-WTC_000087496–000087516

Folder label: “GC/MS Scan 9/20/01

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\HPCHEM\1\DATA\OCTO 2 01\LB.D Vial: 2 Acq On 2 Oct 2001 3:06 pm Operator: 209 GALOS Sample 9/20 Inst : GC/MS 209 Mise : Multiplr: 1,00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library ; C:\DATABASE\NBS75K.L ********************************************************************** Peak Number 12 Tetracosane Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 34.63 1.11 ug/1 168992 Chrysene-dl2 33.16 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Tetracosane 338 C24H50 000646-31-1 91 2 Octadecane 254 C18H38 000593-45-3 91 3 Pentacosane 352 C25H52 000629-99-2 91 4 Heptadecane 240 C17H36 000629-78-7 91 Abundance Scan 3224 (34.635 min): LB.D (-) m/z 57.00 100.00% E7 71 43 85

99 £1 T"^ 34.40 34.60 34.80 35.00 ^^5 I 253 ■ 281,.......... ........... m/z 71.10 73751% ■n/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #73543: Tetracosane 43 57 71

5000- 85 34.40 34.60 34.80 35.00 m/z 43.00 66.87% 99 tn I I l| J ■'27 155169183197 294 338 I " "’I' " ’’I I'''' I' Tife-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #71561: Octadecane

43 57 71 JT"^V 7T 34.40 34.60 34.80 35.00 85 5000 m/z 85.05 55.25%

99 224 2M ‘ I' ' '' p ' ' ' I ' ' ‘ * I I'' ” I ' I'''' I'''' I I ' ' ' ' I ' ' ' * I ' ' ' ' I ■nZz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 Abundance #73718: Pentacosane . TO , I*, , , , £ ?T, I . , , ■ , , , 40 5,7 34.40 34.60 34.80 35.00 in/z 55.00 25.04% 71 5000 85

j | P127141155169183197211225 A'l I r I 11" I I I I I I n I I I 111 I I I* I I I') I < I 11 i i । |-u .. । I'''' I'''' r ‘ ' I nfe-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 34.40 34.60 34.80 35.00 .

LB.D NP091101.M Wed Oct 03 10:10:09 2001 Page 12

NYC-WTC_000087513

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NYC-WTC_000087513Source: NYC Law Department, mirrored locally

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