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Document / 13 pages

GCMS calibration table for TCLP analysis, Oct 25 2001

Machine-extracted title · confidence 95%

Calibration data sheet listing surrogate compounds and retention times for GC/MS instrument used in TCLP testing on October 25, 2001.

NYC-WTC_000067739–000067751

Folder label: “GCMS Scan X 10/5/01 An 10/25/01”

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NYC 9/11 Public Portal Document

Library Search Confound Report Data File : C:\HPCHEM\1\DATA\OCT2501\LB.D vial: 2 Acq On : 25 Oct 2001 11:58 am Operator: 209 GALOS Sample : lab blk 10/5 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\NP101901.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 3-Hexanol Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 6.60 0.42 ug/1 72230 1,4-Dichlorobenzene-d4 11.74 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 3-Hexanol 102 C6H14O 000623-37-0 83 2 Oxiran^ tetramethyl- 100 C6H12O 005076-20-0 58 3 3 - Pen^^nol 88 C5H12O 000584-02-1 45 4 3-Hydroxy-3-methyl-2-butanone 102 C5H10O2 000115-22-0 38 Abundanro^ Scan 169 (6,598 min): LB.D (-) m/z 59705 100700% 50

5000 73 43

6.y 6,40 6.60 6.80 7.00 i„„|t?^ilili|.,„pV. 85 100 I ■ I I I a f I 1 I I I i I • ■ I I I > 1 ( I I . I I I I I ■-] m/z 55.00 83.58% mZz-> 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 Abundance

L #63527:3-Hexanol 50

5000 73 31 6.20 6X0 6.60 6.80 7.00 m/^ 73.00 46.86% 45 11* >11' I"! Tnj +u 84 IpTTTpTTTpTrrpnTrjTTTTpT^^ ■nfe-> 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 Abundance #1579: Oxirane, tetramethyl- 5b 43 ‘ 1 ‘ ‘ 6.y ' I ' ‘ 6,40 6.60 6.80 7.00 »X)0 m/z 43.00 30.74% 31

'nfe-> 5 Abundance 10 15 20 25 45 w ‘ re' /b '75'^ '^‘‘^'iro #62943:3-Pentanol 6.^ “mTz w 6,40 41.05 6.60 6,80 . 7.00 22.14% 31 5000

41

mfe-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 6.20 6,40 6.60 6,80 7.00

LB.D NP101901.M Mon Oct 29 09:51:49 2001 Page 3

NYC-WTC_000067747

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NYC-WTC_000067747Source: NYC Law Department, mirrored locally

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Multi-page laboratory log table recording sample extraction details including volumes and drip rates for GCMS analysis in November 2001.

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