GCMS reference standard analysis, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\l\DATA\MAR3002\REFA2.D Vial: 28 Acq On : 30 Mar 2002 7:44 pm Operator: Sample : gc/ms scan 3/8 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant .Time: Apr 2 15:15 2002 Quant Results File: GCMS0308.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Mar 29 10:31:28 2002 Response via : Initial Calibration DataAcq Meth : GCMS0308

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.25 152 459718 20.00 ug/1 -0.10 10) Naphthalene-d8 15.89 136 1692639 20.00 ug/1 -0.11 17) Acenaphthene-dlO 21.19 164 955155 20.00 ug/1 -0.12 29) Phenanthrene-dlO 25.64 188 1380994 20.00 ug/1 -0.13 38) Chrysene-dl2 33.70 240 746462 20.00 ug/1 -0.15 44) Perylene-dl2 37.94 264 422235 20.00 ug/1 -0.19

System Monitoring Compounds 37) 2,4-DDD 30.71 235 82812 5x^8 ug/mL 0.21 Spiked Amount 5.000 Recovery = 1J^O% Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.89 74 85852 5.50 ug/1 # 69 3) bis(2-Chloroethyl)ether 11.64 93 210721 8.39 ug/1 90 4) 1,3-Dichlorobenzene 12.15 146 150560 5.80 ug/1 98 5) 1,4-Dichlorobenzene 12.30 146 160493 6.17 ug/1 100 6) 1,2-Dichlorobenzene 12.81 146 164994 6.80 ug/1 99 7) 2,2'-oxybis(1-Chloropropan 13.13 45 291616 8.25 ug/1 98 8) N-Nitroso-di-n-propylamine 13.52 70 142036 8.69 ug/1 # 84 9) Hexachloroethane 13.66 117 42718 4.39 ug/1 91 11) Nitrobenzene 13.93 77 193578 8.37 ug/1 93 12) Isophorone 14.57 82 425950 . 9.71 ug/1 99 13) bis(2-Chloroethoxy)methane 15.26 93 262066 9.12 ug/1 98 14) 1,2,4-Trichlorobenzene 15.78 180 142787 7.19 ug/1 95 15) Naphthalene 15.94 128 553130 8.84 ug/1 99 16) Hexachlorobutadiene 16.49 225 44627 4.51 ug/1 97 18) Hexachlorocyclopentadiene 18.69 237 12925 2.00 ug/1 # 94 19) 2-Chloronaphthalene 19.45 162 337195 8.22 ug/1 94 20) Dimethylphthalate 20.53 163 480152 . 9.99 ug/1 99 21) 2,6-Dinitrotoluene 20.75 165 99722 8.55 ug/1 # 81 22) Acenaphthylene 20.72 152 524469 8.95 ug/1 99 23) Acenaphthene 21.28 153 368784 9.00 ug/1 99 24) 2,4-Dinitrotoluene 21.92 165 126542 8.11 ug/1 # 76 25) Diethylphthalate 22.67 149 460878 9.88 ug/1 95 26) 4-Chlorophenyl-phenylether 22.83 204 198773 9.95 ug/1 91 27) Fluorene 22.81 166 413849 9.55 ug/1 98 28) Azobenzen/ 1,2-Diphenylhyd 23.29 77 392965 7.86 ug/L # 86

(#) = qualifier out of range (m) = manual integration REFA2.D GCMS0308.M Tue Apr 02 15:16:29 2002 Page 1

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