GCMS calibration table for TCLP analysis, February 2002

NYC 9/11 Public Portal Document

Data File : C:\HPCHEM\1\DATA\FEB11O2\831.D Vial: 21 Acq On : 12 Feb 2002 5:39 am Operator: 209 GALOS Sample : GC/MS SCAN 1/15 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 Furan, 2,3-dihydro-4-methyl- Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

6.95 0.36 ug/1 32520 1,4-Dichlorobenzene-d4 12.35

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Furan, 2,3 -dihyaro-4 -methyl 84 C5H80 034314-83-5 50 2 2-Pentenal, (E)- 84 C5H80 001576-87-0 50 3 2H-Pyran, 3,4-dihydro- 84 C5H80 000110-87-2 47 4 2-Butenal, 2-methyl-, (E)- 84 C5H80 000497-03-0 43 Abundance Scan 207 (6.947 min): 831 b (-) m/z 83.90100.00% 55 S 39

5000

50 T1

m/z- -l20 25 30 35 ,I,.11.11 — 44|47 III 69 -PPP • I"111" " i 40 45 50 55 60 65 70 75 80 85 90 m/z 6.60 6.80 7.00 7.20 79.98% Abundance #557: Furan. 2.3-dihydro-4-methyl- 55 84

AA 5000 41 ' ' 1 T1il 27 6.60 6.80 7.00 7.20 69 m/z 39.05 72.32% m/z-’ | 37 1 ■ ■ i •'1 11 '1' ■ i' •' ■ i ’' '11 20 25 30 35 40 44—lH 45 50 55 60 ■ i ■ • ■ • i > ■ • • i ■ • ■ > i ■ ■ 65 70 75 80 85 i ■ ’ ■ ■ i ■ ■ ■ ■ i 90 Abundance 55 AA-AAA— ' • i ■ ■ ■ ■ i ■ 27 6.60 6.80 7.00 7.20 4 39 34 5000 m/z 41.05 66.08%

51 66 33 ‘ ‘AI‘‘‘II‘‘‘‘I‘‘‘IJ‘‘*Vm*‘‘VI‘‘‘‘I‘‘‘‘I‘SV‘W‘V‘A‘‘S*I*‘*‘I‘ IVItVUUIIUIIS mi7-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 Abundance #62718: 2H-Pyran. 3,4-dihydro- AAADAMy " 1 ' 55 84 .... 6.60 6.80 7.00 7-20 _ m/z 82.95 '57.50% 5000

41 .............................. 44 51 69 m/z-> ‘I‘1111‘11‘ 1‘TIVuVOI—TTTTr 20 25 30 35 40 45 TT+r '1'' 11''' I''' ‘ I > > I 111' I 111 50 55 60 65 70 75 80 I ■ ■ ■ ■ । ■ • ■ • । 85 90 PP 114 6.60 6.80 44........ 7.00 7.20

831 .D GCMS0208.M Tue Feb 19 10:35:31 2002 Page 1

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