GCMS analysis results for sample AE01047, March 2002

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\l\DATA\022802\01047FB.D vial: 16 Acq On : 28 Feb 2002 11:15 pm Operator: McLean Sample : GC MS SCAN 2/27 Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1\5973N\5080202.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 4 (E)-4-(2',6',6'-Trimethyl-1... Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

37.42 0.46 ug/L 111974 Perylene-d12 34.20

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 (E)-4-(2',6',6'-Trimethyl-1'-eye... 206 C14H22O 089128-17-6 52 2 Pyrrolidine, 1-(9-borabicyclo[3.... 191 C12H22BN 022516-41-2 49 3 (Z)-4-2',6',6'-Trimethyl-2'-cycl... 206 C14H22O 093175-79-2 46 4 2 -METHYLENEHYDRAZONO-3-METHYL-2, . . . 191 C9H9N3S 063149-32-6 43 Abundance Scan 3786 (37.416 min): 01047FB.D (-) m/z 191.15 100.00% 191 4 5000 69 81 55 95 109 123 1 37 150 163 177 205 MarAw ‘Ww 37'00 3/20 37.40 37.60 37.80 l.l. . ,l Illi m/z 69.10 48.63% m/z-> 20 40 60 80 100 120 140 160 180 200 Abundance #1 24499: (E)-4-(2',6',6'-Trimethyl-1'-cyclohexen-1 '-yl)-3-... 191 myubowo 5000 T 43 37.00 37.20 37.40 37.60 37.80 123 m/z 81.10 48.17% 95 107 136 149 206 163

m/z—> 0 Abundance 20 40 60 80 100 120 140 160 180 200 #101795: Pyrrolidine, 1-(9-borabicyclo[3.3.1]non-9-yl)- 191 17— IuW 37.00 37.20 37.40 37.60 37.80 5000 m/z 55.10 39.12%

MmaWwoy 82 95 108 148 40 54 67 122 137 1 162 27 i

m/z-> 0 ,4,44 44444444 20 40 60 80 4444 Ppe 100 120 140 160 180 200 1 176 1 ■ i ' '

Abundance #124501: (Z)-4-2‘,6‘,6‘-Trimethyl-2‘-cyclohexen-1‘-yl)-3-p... 191 37.00 37'20 37.40 37.60 37.80 m/z 95.10 35.42%

5000 43 91 107 123 135 149 | .163 206 Wuu m/z— > 0-IPPPP 20 40 60 80 100 120 140 174 — 160 180 200 T 37.00 37.20 37.40 37.60 37.80

H047FB.D 5080202.M Wed Mar 13 11:03:37 2002 Page 6

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