GCMS calibration data file for sample GC/MS SCAN 1/15, Feb

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\l\DATA\FEB1402\REF.D Vial: 4 Acq On : 14 Feb 2002 11:36 am Operator: 209 GALOS Sample : GC/MS SCAN 1/15 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 19 12:34 2002 Quant Results File: GCMS0208\RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Feb 13 11:43:23 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Mi

1) 1,4-Dichlorobenzene-d4 12.35 152 324901 20.00 ug/1 0.00 10) Naphthalene-d8 15.99 136 1245494 20.00 ug/1 0.00 17) Acenaphthene-diO 21.31 164 667254 20.00 ug/1 0.00 29) Phenanthrene-dlO 25.75 188 983111 20.00 ug/1 -0.01 38) Chrysene-dl2 33.82 240 694424 20.00 ug/1 -0.02 44) Perylene-dl2 38.11 264 448902 20.00 ug/1 -0.01

System Monitoring Compounds 37) 2,4-DDD 30.83 235 45135 4.57 ug/mL 0.33 Spiked Amount 5.000 Recovery = 91.40%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.98 74 18471 ‘ 1.42 ug/1 96 3) bis(2-Chloroethyl)ether 11.73 93 45712 Q.14ug/1 96 4) 1,3-Dichlorobenzene 12.25 146 41522 1.63 ug/1 97 5) 1,4-Dichlorobenzene 12.39 146 44111m 1.70 ug/1 6) 1,2-Dichlorobenzene 12.91 146 42707 1.73 ug/1 97 7) 2,21-oxybis(1-Chloropropan 8) N-Nitroso-di-n-propylamine 13.22 13.62 45 70 74556 34420 Q.31uq/1 (2.25 ug/1 95 97 9) Hexachloroethane 13.76 117 13037 1.26 ug/1 98 11) Nitrobenzene 14.03 77 47269 1.85 ug/1 100 12) Isophorone 14.68 82 94305 (2.Bug/1 100 13) bis(2-Chloroethoxy)methane 15.36 93 57863 -215ug/1 99 14) 1,2,4-Trichlorobenzene 15.87 180 38189 1.79 ug/1 96 15) Naphthalene 16.05 128 139755 2.11 ug/1 100 16) Hexachlorobutadiene 16.59 225 15728 1.23 ug/1 94 18) Hexachlorocyclopentadiene 18.79 237 1987 N.D. 19) 2-Chloronaphthalene 19.56 162 86607 2.18 ug/1 99 20) Dimethylphthalate 20.64 163 114529 247 ug/1 99 21) 2,6-Dinitrotoluene 20.86 165 16538 157uq/1 96 22) Acenaphthylene 20.83 152 121142 C211ug/1 98 23) Acenaphthene 21.39 153 94709 2.36 ug/1 98 24) 2,4-Dinitrotoluene 22.03 165 19503 1.47 ug/1 # 96 25) Diethylphthalate 22.78 149 119791 2.49 ug/1 100 26) 4-Chlorophenyl-phenylether 22.93 204 50771 245 ug/1 96 27) Fluorene 22.92 166 102206 (2.33 ug/1 100 28) Azobenzen/ 1,2-Diphenylhyd 23.40 77 111168 2.19 ug/L 98

(#) = qualifier out of range (m) = manual integration REF.D GCMS0308.M Thu Mar 14 15:21:51 2002 Page 1

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