GCMS analysis results for sample AE00842, Feb 2002

NYC 9/11 Public Portal Document Data File : C:\MSDCHEM\1\5973N\02FEB07\00842.D Vial: 6 Acq On : 7 Feb 2002 6:34 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 7, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP020702.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 10 4-METHOXY-.BETA.-METHYLCINN... Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

22.28 0.13 ug/L 89734 Phenant hrene-d10 22.63

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 72 2 Phenanthrene, 9-methyl- $$ 9-Met... 192 C15H12 000883-20-5 59 3 N-perdeuteriobenzylideneaniline 192 C13D11N 000538-51-2 58 4 2-CYANOCARBAZOLE $$ 9H-Carbazole... 192 C13H8N2 057955-18-7 50 Abundance Scan 1656 (22.280 min): 00842.D (-) m/z 192.10 100.00% 192

5000

82 96 146 160 vr .... s..... i 22.00 22.20 22.40 22.60

m/z-> 0 - 118 •' i" ■ I r ■'' i ■ ■ ■' i

20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 1 ''I > । ■ । ■ 11 >111111 >111 1v m/z 191.10 16.53% Abundance #102588:4-METHOXY-.BETA.-METHYLCINNAMIC ACID $$ 2-Butenoi... 192

108 5000 22.00 22.20 22.40 22.60 146 175 m/Z 193.10 15.89% 0 n i ■ ■'' r ■ • ■ i " ■ ■ i1 ■ ■11 ■ "' i ■ •'' r ’ ■11 111 rTrtr 111 u 111 ' r " ' i ■ " ' r ■i ■ l ■■ ■ ■ I1 1’1 m/z--> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #103936: Phenanthrene, 9-methyl- $$ 9-Methylphenanthrene 192

22.00 22.20 22.40 22.60 5000 m/z 146.10 14.19%

m/z--> Abundance 0 88 26 139 152 165 176 ■'r■ ■ ■ i " "r1" i■' "i’' ■' r■■11 ■11'i " ■' r ■ "r ■ ■ ■ i " "i ■ ■" i11"i' ''' i "1'i■''''I 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 #88409: N-perdeuteriobenzylideneaniline , u , ............ A..................... 192 22.00 22.20 22.40 22.60 m/ z 96.00 13.33%

5000 82

54 110 30 1 94 160 0 — r"■i i" " I 111>' । Fl 111" ■ 11 r111111111"11111111'1"1 r111111 rl Th m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.00 22.20 22.40 22.60

00842.D HP020702.M Thu Feb 21 09:58:10 2002 Page 12

NYC-WTC_000052266