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GCMS surrogate recovery results for sample AE00278, Jan 2002

Machine-extracted title · confidence 90%

Laboratory record documenting GCMS surrogate recovery data for sample AE00278 analyzed on January 10, 2002.

NYC-WTC_000050856–000050874

Folder label: “GCMS X 1/7/02 A 1/9/02

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Scanned page image, NYC-WTC_000050867
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NYC 9/11 Public Portal Document Data File : C:\MSDCHEM\l\5973N\02JAN09\278.D Vial: 3 Acq On 9 Jan 2002 7:50 pm Operator: ■ Sample : 508 scan ext 1/7 Inst : Instrumen Mise : January 9, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 5 4-METHOXY-.BETA.-METHYLCINN... Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T.

22.28 0.15 ug/L 130434 Phenanthrene-dl0 22.63

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 64 2 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 59 3 Phenanthrene, 9-methyl- $$ 9-Met... 192 C15H12 000883-20-5 59 4 Phenanthrene, 1-methyl- 192 C15H12 000832-69-9 59 Abundance Scan 1656 (22.280 min): 278.D (-) m/z 192.10 100.00% 1912

5000

40 49 66 22 82 96| 146 160 22.00 22.20 22.40 22.60 0 118 ■ ■11... ■ i ■. -H m/z 191.10 15.30% m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #102588: 4-METHOXY-.BETA.-METHYLCINNAMIC ACID $$ 2-Butenoi... 192

108 5000 22.00 22.20 22.40 22.60 146 175 m/z 96.00 13.97% 0 ' ' I " 1 ' I ' 1 ' j ' i । । | ' » ' ' | » r i I | । I > i ] i i i ■ i ■ ■■■।■ I ■ ■ '■I........ m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #103930: Phenanthrene, 2-methyl- 192 11i11'1i 1’1111 ' i ' ' 22.00 22.20 22.40 22.60 5000 m/z 146.10 13.74% fl 96 165 176

/z-> 88 l 139 152 On ■ > । ■ ■ ■ ■ ।1 ■ ■ • i • • • > i ■ • • ■ i ■ ■ ■11 ■ 11 > I <1 > ■ i ■ • ■ ■ i > ■ > ■ i > ■ ■ ■ i ■ ■ > • i'" > i —+ TTTTT 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 m+ 1101

Abundance #103936: Phenanthrene, 9-methyl- $$ 9-Methylphenanthrene . ....................... .9. 192 22.00 22 20 22.40 22.60 m/z 193.10 13.74%

5000

96 165 88 l 139 152 J 176 TIITTUupmtmmuumnm—nn*n—*—m—*o"—mn .1 . TTT‘‘IB—n0m3 m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.00 22.20 22.40 22.60

278.D SCAN508.M Thu Jan 10 11:51:44 2002 Page 7

NYC-WTC_000050867

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NYC-WTC_000050867Source: NYC Law Department, mirrored locally

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