GCMS results for sample AE00702, Jan 29 2002

NYC 9/11 Public Portal Document

—— 1

Data File : C:\MSDCHEM\1\5973N\02JAN16\00702.D Vial: 2 . Acq On : 16 Jan 2002 3:57 pm Operator: Sample : 508scan Inst : Instrumen Mise : January 16, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\l-..\SCAN508.M (RTE Integrator) Title : 508 scan method Library- : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 8 D-Limonene Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T. 10.10 1.23 ug/L 450461 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 D-Limonene 136 C10H16 005989-27-5 97 2 D-Limonene 136 C10H16 005989-27-5 97 3 dl-Limonene $$ Cyclohexene, 1-me... 136 C10H16 000138-86-3 97 4 dl-Limonene $$ Cyclohexene, 1-me... 136 C10H16 000138-86-3 97 Abundance Scan 589 (10.098 min): 00702.D (-) m/ z 68.10 100.00% 68 93

5000 79 41 53 107 121 136 . • i • ■ . ■tt”> i ■ । । ।

m/z-> 0 30 —+ -lla, l 1',.. Jb.86,11 IJ, | , 40 50 60 70 80 90 100 11 1 • ' 1 ' ■ ■ i ■ ■ 110 120 130 140 m/z 9.80 10.00 10.20 10.40 67.10 72.70% Abundance #31979: D-Limonene 63

......................................... 93 5000 ' i 1 1 9.80 10.00 10.20 10.40 53 79 107 121 136 m/ z 93.10 72.22%

m/z-> 0 i ■ ■ ' ' i ' 1 r ' i ■ • 1 ■ i ' ■ 30 40 50 60 70 ... |‘.... I 80 90 100 i............ ................ ..

110 120 130 140 Abundance #31983: D-Limonene 63

93 9.80 10.00 10.20 10.40 5000 m/ z 79.10 31.51% 53 79 107 121 136

m/z-> 0 । । । । IT 30 40 1 TI 11 1 1 1 1 1 50 60 70 80 .... . ..... II 90 100 110 120 130 140 Abundance #32003: dl-Limonene $$ Cyclohexene, 1-methyl-4-(1-methylet... ----- 68 9.80 10.00 10.20 10.40 m/ z 94.10 27.65% 93 5000

79 53 107 121 136 Ai rr v । , 0 .................. I........ i ■ ■ ■ ■ i ' ■ 1 ■ i ■ ■ ■ ■ i ■ ■ .. Ijl, ... I ' "'I I " ...I.... ..I... m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 9.80 10.00 10.20 10.40

30702.D SCAN508.M Thu Jan 17 08:17:23 2002 Page 10

NYC-WTC_000051908