GCMS data file header for sample AE00700, Jan 16 2002

NYC 9/11 Public Portal Document

Data File : C: \MSDCHEM\1\5973N\02JAN16\00700.D Vial: 5 Acq On : 16 Jan 2002 2:11 pm Operator: Sample : 508scan Inst : Instrumen Mise : January 16, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N. L ********************************************************************* Peak Number 3 dl-Limonene $$ Cyclohexene,... Concentration Rank 8 R.T. EstConc Area Relative to ISTD R.T. 10.10 0.27 ug/L 99374 1,4-Dichlorobenzene-d4 9.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual

I dl-Limonene $$ Cyclohexene, 1-me... 136 C10H16 000138-86-3 98 2 dl-Limonene $$ Cyclohexene, 1-me... 136 C10H16 000138-86-3 95 3 l-Limonene $$ Cyclohexene, 1-met... 136 C10H16 005989-54-8 95 4 dl-Limonene $$ Cyclohexene, 1-me... 136 C10H16 000138-86-3 95 Abundance Scan 589 (10.098 min): 00700.D (-) m/z 68.10 100.00% 68 93 5000 79 41 53 107 121 136 ■ i ■ 1 TTr" 9.80 10.00 10.20 10.40 0 1 I ■ । ■ । ■ ■ ■ 1 । ■ || 1 ' '90J 1110011'11110H 11 120 112 1 i ■ 1 m/z 67.10 69.10% m/z-> 30 40 50 60 70 80 130 140 Abundance #31993: dl-Limonene $$ Cyclohexene, 1-methyl-4-(1-methylet... 68 93

5000 79 TTTddnd 53 9.80 10.00 10.20 10.40 107 121 136 m/z 93.10 55.78% OT ' ' i ' 1 1 ' i ' ' ' 1 i ' ' । ' > |1 ... I..........Il.......... ..................... 1 ■ I ' 1 ' 1 i • ' 1 1 i ■ 1 ■ ' i ■ ■ 1 i ' m/z~> 30 40 50 6070 80 90 100 110 120 130 140 Abundance #31986: dl-Limonene $$ Cyclohexene, 1-methyl-4-(1-methylet... 68 93

9.80 10.00 10.20 10.40 5000 79 m/z 79.10 40.91% 53 107 121 136

OTTT ■ ■ । ■ 1 1 ■ । ■ ■ ■ ■ । ■ ■ 1..... .............. ' ■ i m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 .. Abundance #32008: l-Limonene $$ Cyclohexene, 1-methyl-4-(1-methy!eth... 68 9.80 10.00 1020 10.40 93 m/z 94.10 28.00%

5000 79 53 107 121 136 1 ------- 0- 1 1 r1 ‘FII‘14." i ' ' ■ ■ । ■ i • ■ i • i ■ < ■ 1 j • - < > t m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 9.80 10.00 10.20 10.40

30700.D SCAN508.M Thu Jan 17 08:17:10 2002 Page 5

NYC-WTC_000051831