GCMS results for sample AE00737, Jan 29 2002

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\1\5973N\02JAN16\00737.D Vial: 5 . Acq On : 16 Jan 2002 6:26 pm Operator: Sample : 508scan Inst : Instrumen Mise : January 16, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 9 dl-Limonene $$ Cyclohexene,... Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T.

10.10 0.13 ug/L 50239 1,4-Dichlorobenzene-d4 9.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 dl-Limonene $$ Cyclohexene, 1-me... 136 C10H16 000138-86-3 94 2 dl-Limonene $$ Cyclohexene, 1-me... 136 C10H16 000138-86-3 87 3 dl-Limonene $$ Cyclohexene, 1-me... 136 C10H16 000138-86-3 87 4 dl-Limonene $$ Cyclohexene, 1-me... 136 C10H16 000138-86-3 87 Abundance Scan 589 (10.098 min): 00737. D (-) m/z 68.10 100.00% 68 93

5000 41 79 53 107 121 136 I’’’

/z-> 0-1 20 ■ i • ■ 1 1 I ' ■ ■ ■ ...

30 40 50 ■ i •

60 I '■''I'+ 70 90 100 110 120 130 80 —L 140 m/z 9.80 1000 10.20 10.40 67.10 77.83% Abundance #31999: di-Limonene $$ Cyclohexene, 1-methyl-4-(1-methylet... 68 93 5000 79 9.80 10.00 10.20 10.40 27 53 136 107 121 m/ z 93.10 76.14%

rn/z-> 0 ■ i ' ' ' ' i 1 • ■ ■ I ■ ' ■ 1 i ■ ' ■ ■ i ' 20 30 40 50 60 70 L80 90 100 110 120 130 140 Abundance #31996: dl-Limonene $$ Cyclohexene, 1-methyl-4-(1-methylet... 68 9.80 10.00 10.20 10.40 93 5000 m/ z 97.10 43.08%

79 121 136 I 53 107

mlz~> 0 11'1111 '11' r 20 30 40 I. 1 I ’ ' ' ' I ' 50 60 । ■ ■ ■' i ■ ■ ■ ■ r1 70 80 90 100 110 120 130 140 i ■ । • ■ ■ ■ । ■ X Abundance #32003: di-Limonene $$ Cyclohexene, 1-methyl-4-(1-methylet... 68 9.80 10.00 10.20 10.40 m/z 94.10 36.85% 93 5000

79 53 107 121 136

■n/z-> 20 30 40 50 60 70 .. ’I1.. II 80 90 100 110 120 -4 130 140 9.80 ‘d" 1 i > > ‘ • i ■ ■ ■ ’ i 10.00 10.20 10.40

30737.D SCAN508.M Thu Jan 17 08:17:41 2002 Page 11

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