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GCMS surrogate recovery results for sample AE00316, Jan 2002

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Laboratory record documenting GCMS surrogate recovery data for sample AE00316 analyzed on January 10, 2002.

NYC-WTC_000050963–000050976

Folder label: “GCMS X 1/7/02 A 1/9/02

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NYC 9/11 Public Portal Document Data File : C:\MSDCHEM\l\5973N\02JAN10\00316.D Vial: 3 Acq On : 10 Jan 2002 10:07 am Operator: Sample : 508 scan ext 1/7 Inst : Instrumen Mise : January 10, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1...\SCAN508. M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 5 3-Cyanocarbazole $$ 9H-Carb... Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 22.28 0.13 ug/L 66884 Phenanthrene-dl0 22.63 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Cyanocarbazole $$ 9H-Carbazole... 192 C13H8N2 057102-93-9 64 2 2-CYANOCARBAZOLE $$ 9H-Carbazole. . . 192 C13H8N2 057955-18-7 64 3 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 64 4 Phenanthrene, 9-methyl- $$ 9-Met... 192 C15H12 000883-20-5 59 Abundance Scan 1656 (22.280 min): 00316. D (-) m/z 192.10 100.00% 192

5000

„ 96 146 160 66 82 I 22.00 22.20 22.40 22.60

m/z-> 44 0 " i " "i " -H 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 ......... 'I... I.. mmm - m/z 193.00 15.55% Abundance #103424: 3-Cyanocarbazole $$ 9H-Carbazole-3-carbonitrile (CAS 192

5000 22.00 22.20 22.40 22.60 96 164 m/z 96.00 15.27% | 138 0 ■ i1 ■ ■ ■ i ■ ■ ■ ■ i ■'' ■ i ■ ' i " " i' ■'' r " ' i " 11111111 4 I " '111 " 111 ' 11 ‘' m/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #103420: 2-CYANOCARBAZOLE $$ 9H-Carbazole-2-carbonitrile (CAS 192

22.00 22.20 22.40 22.60 5000 m/z 191.10 14.31%

96 164 1 138 II 0 '11' " ' I " " i " '' i' " ' i'' " i'''' r " ' i " " I ■ " ''I " ' l'| >> rrm rr, 11111111 111 > > 111 nr mlz-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #102588: 4-METHOXY-.BETA.-METHYLCINNAMIC ACID $$ 2-Butenoi... TT 192 22.00 22.20 22.40 22.60 m/z 146.10 14.05% 108 5000

146 175

0 '' i' " ' i' ’ " i ■ " ■ r - TT’’’ 11II111111111 ■ I ■ " ■ r ■1 ■ i • 1' i1"1 r A — ■ i " " i • " • r ■ TTT I ′′′ T m/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.00 22.20 22.40 22.60

00316.D SCAN508.M Thu Jan 10 11:52:13 2002 Page 7

NYC-WTC_000050974

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NYC-WTC_000050974Source: NYC Law Department, mirrored locally

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