GCMS analysis results for sample AD31643, Jan 28 2002

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Data File : C:\MSDCHEM\1\5973N\02JAN17\31643.D Vial: 3 ' Acq On : 17 Jan 2002 4:29 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 17, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 7 4-METHOXY-.BETA.-METHYLCINN... Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 22.28 0.14 ug/L 82982 Phenanthrene-dl0 22.65 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 4-METHOXY-.BETA.-METHYLCINNAMIC ... 192 C11H1203 019169-94-9 72 2 3-Cyanocarbazole •$$ 9H-Carbazole... 192 C13H8N2 057102-93-9 64 3 1,3-Benzodioxole, 4-methoxy-6-(2... 192 C11H12O3 000607-91-0 52 4 2-CYANOCARBAZOLE $$ 9H-Carbazole... 192 C13H8N2 057955-18-7 50 Abundance Scan 1656 (22.280 min): 31643.D (-) m/z 192.10 100.00% 192

5000 . ...... .. ........... 44 70 82 ? 0- TIITTTT •hmpapmmmmmmpm 146160 1ll— 22.00 22.20 22.40 22.60 m/z 191.10 15.15% nz-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #102588: 4-METHOXY-.BETA.-METHYLCINNAMIC ACID $$ 2-Butenoi... 192

108 - 5000 22.00 22.20 22.40 22.60 146 175 m/z 193.10 14.87% 0 ‘ I‘‘‘*44*4*m*/**A141‘‘‘‘1‘44‘154 l ■ ■ i ■ | ‘ ■ ' ' ! “ ' • | ■ ' I " ' ‘ I " ‘ ' I ‘ Hunt miz-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #103424:3-Cyanocarbazole $$ 9H-Carbazole-3-carbonitrile (CAS 192 — 22.00 22.20 22.40 22.60 5000 m/z 96.00 14.78%

96 164

niz—> ....... .......... |....... ............. Oi 1112211111110111/111111/22/113153/1111111331109012/331111231" 40 50 60 70 80 90 1(X) 110 120 130 140 150 160 170 180 190 200 L 1'i “ ■' i “ ' ■ i11" i ■1

Abundance #102624:1,3-Benzodioxole, 4-methoxy-6-(2-propenyl)- (CAS)... 1 ■ i ' ' ■ ■ i ■ ■ ■ ■ i • ■ ■ • i ■ ■ 19/2 22.00 22.20 22.40 22.60 m/z 146.10 13.39% 5000

91 165

iz-> I 103 119 131 II 147 0- 111" " r ■ “ 11" 11'1'11" 1 r i ■' | 111—001I —0010100uTr I 177 — 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 l A ■ • i ■ ■ ■ ■ । ■ ■'' । 22.00 22.20 22.40 22.60 ■ i ■'

31643.D SCAN508.M Tue Jan 22 08:37:13 2002 Page 9

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