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GCMS analysis results for sample AD31637, Jan 28 2002

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Laboratory report showing GCMS analysis of sample AD31637 including unknown compounds and surrogate recovery data.

NYC-WTC_000049929–000049943

Folder label: “GCMS X 1/3/02 A 1/17/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C: \MSDCHEM\1\5973N\02 JAN17\31637 . D Vial: 4 ‘ Acq On : 17 Jan 2002 12:42 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 17, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 7 N-perdeuteriobenzylideneani... Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T. 22.28 0.14 ug/L 81654 Phenanthrene-dl0 22.65 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 N-perdeuteriobenzylideneaniline 192 C13D11N 000538-51-2 64 2 Phenanthrene, l-methyl- 192 C15H12 000832-69-9 53 3 Phenanthrene, 9-methyl- $$ 9-Met... 192 C15H12 000883-20-5 53 4 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 53 Abundance Scan 1656 (22.280 min): 31637.D (-) m/z 192.10 100.00% 1512

5000

146 160 22.00 22.20 22.40 22.60 120 0 .. ।. 11. ■. ।।. 1. TDHTT —I]H wpe m/z 191.10 16.37% /z—> 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 200 Abundance #88409: N-perdeuteriobenzylideneaniline 192

5000 82 22.00 22.20 22.40 22.60 54 110 m/z 193.10 15.33%

m/z—> 30 0 mp T1l‘‘‘‘1‘1441 20 30 40 50 60 70 80 Tpmmpgmt 16094 100 110 120 130 140 150 160 170 180 190 2(» 4 Abundance #103924: Phenanthrene, 1-methyl- 192 T T T T 22.00 22.20 22.40 22.60 5000 m/z 96.10 13.51%

m/z—> 0- 96 152 165 178 , । i p । । । । i । i i । i'i'i । । i i I I । । । i'i i ! i. I.! i i l >. .. I.. I.!.. ,. |. ... |, 11 I'l. (... . I.... | .... | 20 30 40 50 60 70 TO 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #103936: Phenanthrene, 9-methyl- $$ 9-Methylphenanthrene u ' ' i ' ' ‘ ' i ' 1 i ■ ' ■ ■ i ■ 1 152 22.00 22.20 22.40 22.60 m/z82.10 12.43%

5000

96 88 139 152 165 ITS n/z—> 14.176,1 0 11 ].. i . 11 । 11 i 1111 11111 > 111) i 111 ■ i “ “ i1 ‘ ■ i ■ i “ ■ ‘'i'1" i' ■ “ i 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 MO Wgn ........ N. — 22.00 22.20 22.40 22.60

31637.D SCAN508.M Tue Jan 22 08:36:59 2002 Page 9

NYC-WTC_000049941

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NYC-WTC_000049941Source: NYC Law Department, mirrored locally

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