GCMS sample analysis report AE08436, Apr 18 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C: \HPCHEM\1\DATA\APR1202\8436.D Vial: 25 Acq On : 16 Apr 2002 7:35 am Operator: Sample : gc/ms scan 4/10 fb Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 Cyclopentasiloxane, decamethyl Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

14.82 0.30 ug/1 53402 Naphthalene-d8 15.86

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclopentasiloxane, decamethyl- 370 C10H3005Si5 000541-02-6786 2 N-(Trifluor/acetyl)-N,O,O' ,0''-tetr 553 C22H42F3NO4Si4 000000-00-0 43 3 Noradrenaline, tetra-TMS 457 C20H43N03Si4 000000-00-0 37 4 Phenethylamine, N-methyl - . beta . , 3,4 399 C18H37NO3Si3 010538-85-9 37 Abundance Scan 1065 (14.824 min): 8436.D (-) m/z 72.95 100.00% 73

5000 267 355 ........ I I1r I I I I 1 I I I \1......... 1 1II r I I I I I

45 14.40 14.60 14.80 15.00 15.20 — ■ 1 i ■ 125 154 191 223 . 323 ** *i 1 " 1* r' ■ 'l'1 TIT————m—————mTTT m/z 2 67.00 47.68% m/z->______ 50 100 150 200 250 300 350 400 450 500 550 Abundance #51266: Cyclopentasiloxane, decamethyl- 73

355 267 / 5000 Il.T TBl 1 1 i ■ ■ 1 1 i ■ ' 14.40 14.60 14.80 15.00 15.20 m/z 355.05 44.06% IPPBPmm 207—m:323(.................. TTT+ m/z-> 50 100 150 200 250 300) 350 400 450 500 550 Abundance #60162: N-(Trifluoroacetyl)-N,O,O',O”-tetrakis(trimethylsi 73 i ' 1 ■ 1 i r ' 355 14.40 14.60 14.80 15.00 15.20 5000 m/z 356.05 14.26%

45 I i, 147 ■ 'i ■ > ■ 193। ■ ■ ■ ■ । 267' ■ ■■ ■ ■ । ■ ■ • ■ । । j ■ ■ ' ■ ■ I ■ ■ 538 ' 'I ' 11 ' 1 1 m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #57357: Noradrenaline, tetra-TMS 73 14.40 14.60 14.80 15.00 15.20 m/z 268.00 11.17%

5000 102 355

45 1 147 442......... 1. m/z—> 50 100 150 200 250 300 350 400 450 500 550 14.40 14.60 14.80 15.00 15.20

8436.D GCMS0412.M Wed Apr 17 09:48:33 2002 Page 3 NYC-WTC_000048580