GCMS analysis results, Sample AE08263, April 22, 2002

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Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\020417\08263.D Vial: 20 Acq On : 18 Apr 2002 1:07 am Operator: Nefliu Sample : sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\041702SCAN.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 3 l-Buten-3-yne, 2-chloro- Concentration Rank 12

R.T. EstConc Area Relative to ISTD R.T.

3.76 0.20 ug/L 150766 1,4-Dichlorobenzene-d4 9.98

Hit# of 5 Tentative ID MW MolForm CAS# Qual

l l-Buten-3-yne, 2-chloro- 86 C4H3C1 017712-36-6 7 2 2-Butenoic acid, (E)- 86 C4H602 000107-93-7 4 3 2-Fluoroimidazole 86 C3H3FN2 1000129-59-1 2 4 5-Fluoroimidazole 86 C3H3FN2 1000128-06-0 2 Abundance Scan 116 (3.761 min): 08263 D (-114) (-) m/ z 35.10 100.00% 35 86

5000 38 42

47 49 84 88 4l 3.40 JIMI 3.60 3.80। 4.00 4.20 - 0 i■■■■i■■ TIH m/z85.9078.60% 35 40 50 55 60 65 70 75 80 85 90 95 n/z-> Abundance 25 30 45 #34744: 1-Buten-3-yne, 2-chloro- 51 85 ""Ns""MMWny 5000 88 340 3.60 3.80 4.00 4.20 m/z 3 8.10 40.04% 6062 0+ i ■ ■ 1 1 i' 1 ■ ' i 1 1 1 ■ i ■ ■ ■ ■ i ' ' ' I | I I 1 1 | ' rrrtrr r, । . . . . । . . . . , । । । .I | 11'' ■' ।1 n/z-> :25 30 35 40 45 50 55 60 65 70 75 80 85 90 95

min) Abundance #116768: 2-Butenoic acid. (E) 85

41 340 3 60 3.80 4.00 4.20 39 5000 m/z 42.00 38.98% 69 45 71

n/z-> 0+ :25 -364 30 35 | 50 555/ 6062 66 I 75 ।11 I................. 'I "I........... 1111 ■' ।1' ■ ■ ।1' ■ ■ 11 40 45 50 55 60 65 70 75 80 85 — 90 95 AW fl Abundance #34865: 2-Fluoroimidazole 85 340 3 60 380 4.00 4.20 m/z 83.90 29.45%

5000 59 "MparyMMeuh /z-> 41 4446 51 5557 6567 71 0 । ■ ■' * ।> i' > ■ > 1111' 11 n 111111111 H । ■' 1 ' i ■ 1 1 1 i1 ' ' 11 ' 1 ' ■ i ' ' '1 i 25 30 35 . 40 45 50 55 60 65 70 75 80 85 890—95 3.40 360 3.80 ' 4.00 ' 4.20

08263 .D 041702SCAN.M Thu Apr 18 09:51:12 2002 Page 8

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