GCMS results for sample AE08068, Apr 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\020415\08068.D Vial: 25 Acq On : 16 Apr 2002 6:25 am Operator: Nefliu Sample : sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\041202SCAN.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98.L ********************************************************************* Peak Number 2 2-Butene, 1-chloro-2-methyl- Concentration Rank 14

R.T. EstConc Area Relative to ISTD R.T.

4.38 0.53 ug/L 350071 1,4-Dichlorobenzene-d4 9.99 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2-Butene, 1-chloro-2-methyl- 104 C5H9C1 013417-43-1 91 2 3-Methyl-3-chloro-l-butene 104 C5H9C1 002190-48-9 91 3 2-Butene, l-chloro-3-methyl - 104 C5H9C1 000503-60-6 83 4 2-Butene, 1-chloro-3-methyl-______ 104 C5H9C1 000503-60-6 72 Abundance Scan 222 (4 384 min); 08068 D (-214) (-) m/z 69.30 100.00% 41 63

5000 104 53

84 89 4 00 4 20 440 4.60 4.80

n/z-> 0+ ....................... 10 20 30 40 ll 50 ■I ' ' ■ ' I ' - 60 70 80 — 90 100 110 m/z 41.30 88.01% Abundance #114167: 2-Butene. 1-chloro-2-methyl- 41 69

5000 104 53 4,00 4 20 4.40 4 60 4 80 27 m/z 104.20 37.55% — 89 I 0+ +4361 —4 4414 — ——+4+ 63 ,7584 I,...... . I ■ ■ 1 1 i 1 ' 1 1 i ■ ■ ■ ■ i ■ 1 ■ i ■ 1 -n/z--> 10 20 30 40 50 I60 70 80 90 100 110 Abundance #114062: 3-Methyl-3-chloro-1-butene 41 63 .................................................

4.00 4 20 4.40 4.60 4.80 5000 m/ z 39.30 33.03% 53 27 104 15 ........... Z- > 0 ■ 1 I > >'• 10 20 30 40 60 62 —T 1,75. 70 80 90 1‘T - 100 110 Abundance #108770 2-Butene, 1-chloro-3-methyl- 41 69 *dndn—d—n/—D/—m/nm/n 4 00 4 20 440 4 60 4 80 m/z 53.30 27.15% 5000 I 53 104 27

n/z--> 0 10 20 , 36 । , ----- 30 40 50 , 60 31.75.... "....... 70 80 90 100 — 110 1... r..... 4.00 4 20 4 40 4.60 4.80

08068.D 041202SCAN.M Tue Apr 16 13:56:50 2002 Page 5

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