GCMS calibration data for sample AE11931, May 2002

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Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\052302\11931.D Vial: 11 Acq On : 23 May 2002 6:07 pm Operator: Mclean Sample : 5/22ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 4 l-Buten-3-yne, 1-chloro-, (E)- Concentration Rank 14

R.T. EstConc Area Relative to ISTD R.T.

4.02 0.90 ug/L 544930 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual l l-Buten-3-yne, 1-chloro-, (E)- 86 C4H3C1 020374-91-8 38 2 Krypton 84 Kr 007439-90-9 9 3 Phosphonic difluoride 86 F2HOP 014939-34-5/5 4 l-Buten-3-yne, 1-chloro-, (Z) - 86 C4H3C1 020374-90-/ 5 Abundance Scan 161 (4.025 min): 11931.D (-158) (-) m/z 47.10 100.00% 47 84 /...

51 5000 44 38 88 41 3.60 3.80 4.00 4.20 4.40 58 0+ ■ • i ■ • ■ • i ■1 ■ ■ i' ■ 11.8 TI’ ■ ■ i' ■1 ■i1■■ • i ■ " ■ i • ■ ■■ i■1'' i " ■ i ■ ■ ■' i ■ ■ m/z 84.00 91.03% miz-> 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12408:1-Buten-3-yne, 1-chloro-, (E)- 51 85

5000 3.60 3.80 4.00 4.20 4.40 m/z .86.00 80.31% ,' • • i • ‘ 60 0 ■ ■ i ■ ■ ■ ■ i ■1 • ■ i1 • “ i ‘1' ■ i ■ ‘'1

55 60 65 70 ■ I'1 ■ • i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ • ■ ■ i ■' ■11'

75 80 85 IP90 77 95 niz-> 25 30 35 40 45 50 Abundance #33829: Krypton 84

3.60 3.80 4.00 4.20 4.40 m/z 51.10 54.49%

miz-> 5000

01 25 35 42 11J1' “ J “ 1 ■ i ■ " ■ 1111 ‘ i "

30 40 45 50 ***** 80 55 60 65 70 75 80 T 85 ‘' I ‘ 90 ‘ ‘ l ‘ ' 95 /hot Abundance #34889: Phosphonic difluoride 85 3.60 3.80 4.00 4.20 4.40 m/z 44.00 47.48% 5000 69

66 47 31 50 0 11111111111 ■ i ■ ■ • ‘ 11 ■ • ■ i ‘ ■ • i' ■ ■ ■ i ■ ■ ■ ■ i 1’1111111111" ** । • * * * i* * m/z-> 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.60 3.80 4.00 4.20 4.40

11931.D 052202.M Wed May 29 09:50:56 2002 Page 7

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