GCMS calibration table for TCLP extraction method

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052802\12287.D Vial: 6 Acq On : 28 May 2002 6:22 pm Operator: McLean Sample : 5/24 ad Inst : Instrumen Mise Multiplf: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan ** Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 2 4-Chlorobuten-3-yne Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T.

3.74 0.96 ug/L 650388 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-Chlorobuten-3-yne 86 C4H3C1 040589-38-6 43, 2 l-Buten-3-yne, 1-chloro-, (E)- 86 C4H3C1 020374-91-8 38 3 1,2,3-Butatriene, 1-chloro- 86 C4H3C1 020658-21-3 738 4 l-Buten-3-yne, 1-chloro-, (Z) - 86 C4H3C1 020374-90-7 38 Abundance Scan 112 (3.737 min): 12287.D (-110) (-) m/z 49.10 100.00% 49 86

5000 40 43 52 ‘ • i ' • ‘ • i • ■ • ■ i ■ ■ ■ • i ■ • > ■ i 37

n/z-> O—TT 30 —35L40 45 50 — —PPP ■'Tr 55 60 65 70 75 80 85 90 95 m/z 3.40 3.60 86.00 3.80 4.00 83.84% Abundance #12405:4-Chlorobuten-3-yne 51 86

5000 3.40 3.60 3.80 4.00 m/z 51.00 73.78% 60 0- -T - HIPTI 39 ■ ■ i ■ • ■ ■ i ’11111111111 miz-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12408:1-Buten-3-yne, 1-chloro-, (E)- 51 86 * * । 1 1 1 1 i • *.................... ... ‘ । 3.40 3.60 3.80 4.00 5000 m/z 40.00 41.01%

niz-> 0- ■ ■ i ■ ‘ 30 ■ i111' i1111111111 35 40 45 50 tL-r-p-r-rT-j-T-r-r-r-p-r 55 60 6070 75 80 65 ■ ■ i ■ ■ ■ ■ i ■ ‘ i ■■ ■1! +89 85 90 95 Abundance #12404:1,2,3-Butatriene, 1-chloro- ■ ■ i ■ ■ ‘ ' i • ■ ' ■ i 1 ■ ■ ‘ i ■ ■ ■ ■ i 51 86 3,40 3.60 3.80 4.00 m/z 38.10 29.27%

5000 WAMM 0 ■ ■ i ■' ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■1 .' ■ ‘ । ■1 ■'60I ■1111 ■ ■ ■ ■ । ■ ■ ■11 ‘11 ■ । ■ ■ ■11 n/z-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.40 3.60 3.80

12287.D 052202.M Thu May 30 10:40:26 2002 Page 5

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