GCMS analysis results, sample AE12533, June 2002

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Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052902\12533.D Vial: 24 Acq. On : 30 May 2002 4:49 am Operator: McLean Sample : gc/ms scan 5/28 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 5-08 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 9 1,2,3-Butatriene, 1-chloro- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

3.99 1.26 ug/L 997751 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,2,3-Butatriene, 1-chloro- 86 C4H3C1 020658-21-3 8 2 l-Buten-3-yne, 1-chloro-, (Z)- 86 C4H3C1 020374-90-79 3 l-Buten-3-yne, 1-chloro-, (Z)- 86 C4H3C1 020374-9a/7 7 4 l-Buten-3-yne, 1-chloro-, (E)- 86 C4H3C1 020374-91-8 7 m/z 51.10 /100.00%

_us. Abundance Scan 155 (3.990 min): 12533.D (-153) (-) 51 86 35 38 47 5000

3.60 3.80 4.00 4.20 4.40 m/z—> 0- ■ ■ i ■ " ■ i ■ “ ■ i ■ ■ 15 20 25 30 35 npmmpr 40 45 ‘It - 82 - 50 55 60 65 70 75 80 85 90 95 m/z 86.00 89.52? Abundance #12404: 1,2,3-Butatriene, 1-chloro- 51 86

5000 3.60 3.80 4.00 4.20 4.40 m/z 35.10 74.29 60 18930— 95‘I-T n/z-> Of 1 ■ i • “ ■ i ■ ■" i1 •' ■ i ■" ■ i' ■ ■ ■ i ■ ■ ■1 ’ Iampljuli ——mmpott 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 Abundance #12406: 1-Buten-3-yne, 1-chloro-, (Z> V "ht 51 86

3.60 3.80 4.00 4.20 4.40 5000 m/z 47.10 60.00?

26 30 O ’ * | * 1 * * 111 37 +89- 43 48 | । 11 j 11 I 11 i i! I ।«111— —T 60 63 7174 83. ./MMuwr. niz-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #111070:1-Buten-3-yne, 1-chloro-, (Z)- ■ i ‘ ■ i ‘ ■ i ■ ■ ■ ■ i ■ ■ ' ■ i • ' 51 86 3,60 3.80 4.00 4.20, 4.40 m/z 38.00 59.05?

5000

60 n/z-> oR 11900119—m—mmpompoort -mmammmmmmpt 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 189— ‘[U1 3.60 3.80 4.00 4.20 4.40

12533.D 052202.M Mon Jun 03 11:45:29 2002 Page 12

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