GCMS analysis report sample AE09679, May 23, 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052102\9679.D Vial: 17 Acq On : 22 May 2002 2:22 am Operator: Mclean Sample : re-extract Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 9 l-Buten-3-yne, 1-chloro-, (E)- Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. 4.04 0.64 ug/L 405397 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 l-Buten-3-yne, 1-chloro-, (E)- 86 C4H3C1 020374-91-8 56 2 1-Buten-3-yne, 1-chloro-, (Z) - 86 C4H3C1 020374-90-7 56 3 1,2,3-Butatriene, 1-chloro- 86 C4H3C1 020658-21-3/7 4 l-Buten-3-yne, 1-chloro-, (Z) - 86 C4H3C1 020374-90-7 7 Abundance Scan 164 (4.043 min): 9679.D (-162) (-) m/z 86.00 100. 00% 85 51

5000 70 88 41 84

—144 4, 0 58 3.60 3.80 4.00 4.20 - 4.40

A 0- ■ ■ ।' 11 * i > * * * i * * m/z 51.10 74.34% niz-> 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12408:1-Buten-3-yne, 1-chloro-, (E)- 51 85

5000 T 88 3.60 3.80 4.00 4.20 4.40 m/ Z 86.90 30.95% 49 ( 6062 84, 4 0- 1 ■ i 1 ■ • ■ I ‘ • i ■ ■ ■ 11' 1 ■ • i ■ ■ ■ ■ I ■1 ■ ■ i1 ■ ■ ■ i ■ ■ ■ ■ i ■1 ■ ‘ i ■ ‘ '1 I 1 I ' 1 I I I 1 1 miz-> 35 40 45 50 55 60 65 70 -75 80 85 90 95 Abundance #111070:1-Buten-3-yne, 1-chloro-, (Z)- 51 86 18 3.60 3.80 4.00 4.20 4.40 5000 m/z 88.00 30.79%

miz-> 0- ■ ■ i ■ ■' ■ rr i 11111'1 35 40 45 49 50 , 6062 84 '' ■ i1 ■' • I ■1 ■' i • ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■' i • ■ ■1 H 55 60 65 70 75 80 85 88

1 1111 ■ ■ i ■ ■ 90 95 MMMoud Abundance #12404:1,2,3-Butatriene, 1-chloro- 51 86 3.60 3.80 4.00 4.20 4.40 m/z 70.00 27.53 5000 88

49 , 6062 84 0 TIPmt. • > • i • ■ * ■ 1 >1 * ■ i ■ ■ ■ < i ■ ■ ■ ■ j ■ ■ • ■ i ■ • • ■ I r1 1 1 ' 1T1 ■ ■ i • ■ /z-> 35 40 45 50 55 60 65 70 75 80 85 90 95 3.60 3.80 4.00 4.20 4.40

9679.D 052202.M Wed.May 22 11:45:27 2002 Page 12

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