GCMS analysis results, sample AE12533, June 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052902\12533.D Vial: 24 Acq On : 30 May 2002 4:49 am Operator: McLean Sample : gc/ms scan 5/28 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 10 l-Buten-3-yne, 2-chloro- Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T. 4.13 0.82 ug/L 648654 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 l-Buten-3-yne, 2-chloro- 86 C4H3C1 017712-36-6 43 2 1,2,3-Butatriene, 1-chloro- 86 C4H3C1 020658-21-335 3 4-Chlorobuten-3-yne 86 C4H3C1 040589-38-6 32 4 1-Buten-3-yne, 1-chloro-, (Z)- 86 C4H3C1 020374-90-7 25 Abundance Scan 178 (4.125 min): 12533.D (-174) (-) m/z 85.00 100.00% 49 85 41

5000 35 88 44 ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ 1 i ■ ' 1 • I 1 1 1 1 I 3.80 4.00 4.20 4.40 O—TT —I’’ •' i' ■ • ■ i ‘ * i ■ ‘ ■ i ‘ ‘ ' i ■ ■ • ■ i ■ ■ T-p-n-r-p-r m/z 49.10 88.89% miz-> 30 35404550556065 70 75 80 85 9095 Abundance #34744:1-Buten-3-yne, 2-chloro- 51 85

5000 T 3.80 4.00 4.20 4.40 m/z 51.10 86.93% 60 39 0- ’’1B—1IICOIIT-11111r1113 PTTT " 11" ■ ■ i ■' ■' i1" ■ i " i " 11 + Ft "'i" niz-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12404:1,2,3-Butatriene, 1-chloro- 51 86 1 ■ ■ i ' ■ ■ 1 i ■ ■ 1 ■ । ■ i ■ ■ ■ ‘ । 3.80 4.00 4.20 4.40 5000 m/z 86.00 82.68% /.

, 60 0- • ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■11 ' ■ ■ i ■ " • I'' ■ ■ i ■'111''11111111'1111 niz-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12405:4-Chlorobuten-3-yne T T 51 86 3.80 4.00 4.20 4.40 m/z 41.10 81.37% 5000

60

miz-> 0 30 35 40 45 50 ।1 ■ i ■ ‘ ■ ■ 1'1'11 ‘ ‘' i1 * ■ ‘ i ‘' •11' ■ ■ H 55 60 65 70 75 80 85 IP90—m 95 3.80 4.00 4.20 4.40

12533.D 052202.M Mon Jun 03 11:45:30 2002 Page 13

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