GCMS surrogate recovery report, sample AE12283, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\0610022\12283.D Vial: 11 Acq On : 10 Jun 2002 7:10 pm Operator: Sample : gc/ms scan 6/7 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 6 l-Buten-3-yne, 2-chloro- Concentration Rank 13 R.T. EstConc Area Relative to ISTD R.T.

3.90 1.25 ug/L 995708 1,4-dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual

l l-Buten-3-yne, 2-chloro- 86 C4H3C1 017712-36-6 4 2 4-Chlorobuten-3-yne 86 C4H3C1 040589-38-6 4 3 1-Buten-3-yne, 1-chloro-, (E)- 86 C4H3C1 020374-91-8 4 4 1-Buten-3-yne, 1-chloro-, (Z) -______ 86 C4H3C1 020374-90-7 4 Abundance Scan 140 (3.902 min): 12283.D (-139) (-) m/z 86.00 100.00% 35 85 48 43 51 5000 83 ■ ' ' i ' ■ ' ' i ' ■ ■ ■ r‘‘ 1 1 1 I 1 1 1 1 I 70 i 3.60 3.80 4.00 4.20 40 — 0- — TTTTTTT • 1 • । •■ ■ ■ । • m/z 35.10 89.71% miz-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #34744:1-Buten-3-yne, 2-chloro- 5|1 85

5000 ■ • ■ i ■ ■ ■ ■ i ■ 1 ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ I

3.60 3.80 4.00 4.20 m/z / 48.10 73.90% 0- 111'1 ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i1 ■ ■ 60 1'' i111' I'11' i''111'1111111 1111111 +97 miz-> Abundance 30 35 40 45 50 55 60 65 70 75 #12405:4-Chlorobuten-3-yne 80 85 90 95 -W 51 86 ' ‘ 1 i ■ ■ ‘ • i • • ■ • I ' 1 1 1 1 1 1 1 1 I 3.60 3.80 4.00 4.20 | 5000 m/z 43.00 54.23%

60

m/z-> 0- *’1’ 141+’’’1’4111’114.* ।11111111111111'11111111'1111'111 ' 30 35 40 45 55 60 65 70 75 80 50 85 +9—m 90 95 Abundance #12408:1-Buten-3-yne, 1-chloro-, (E)- 10* 51 85 3.60 3.80 4.00 4.20 m/z 51.10 53.49%

5000

i 60 39 0 ' ■ ■ i •' ■ ■ I ■1 ■ ■ i ‘ ■11 ■ ■ ■ ■ i ■' ■ ■ i ■ ■ ■11' 11 ■ ■ ■11 ■ • n/z-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.60 3.80 4.00 4.20

12283.D 060302.M Tue Jun 11 08:23:50 2002 Page 9

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