GCMS reference analysis results for volatile organics, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\l\DATA\060702\12735.D Vial: 11 Acq On 7 Jun 2002 4:43 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 4 4-Chlorobuten-3-yne Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

3.95 2.93 ug/L 2044710 1,4-dichlorobenzene-d4 9.89

Hit# Of 5 Tentative ID MW MolForm CAS# Qual 1 4-Chlorobuten-3-yne 86 C4H3C1 040589-38-6 BO 2 l-Buten-3-yne, 2-chloro- 86 C4H3C1 017712-36-6/42 3 l-Buten-3-yne, 1-chloro-, (Z) - 86 C4H3C1 020374-90-7 38 4 l-Buten-3-yne, 1-chloro-, (E)- 86 C4H3C1 020374-91/8 38 Abundance Scan 149 (3.955 min): 12735.D (-146) (-) m/z .86.00 100.00% 5(1 85

5000 36 40 70

83 3.60 3.80 4.00 4.20 4.40 - 0 ' • < p * * * । ■' i • • ■ ■ i ■ ■ ■11 ■ ■ T-p-r-n-p-T m/z 51.10 95.68% miz-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12405:4-Chlorobuten-3-yne 51 86

5000 3.60 3.80 4.00 4.20 4.40 m/z 84.00 91.73% 60

niz-> 0- h 1 39 30 35 40 45 50 55 60 65 70 75 80 85 90 95 1 n f 1 " I "

Abundance #34744:1-Buten-3-yne, 2-chloro- 51 85

3.60 3.80 4.00 4.20 4.40 5000 m/z 49.10 48.12%

60 39 0- +T r' 'l" niz-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #111070: 1-Buten-3-yne, 1-chloro-, (Z)- 51 86 3.60 3.80 4.00 4.20 4.40 m/z 88.00 43.61%

5000

60 _Mar 0 • ■ i • ■ ‘ ‘ ‘ ‘ i' ■'11''11 +oom0)pe ''39I'1' ‘ I'' /z-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.60 3.80 4.00 4.20 4.40

12735.D 060302.M Mon Jun 10 11:22:45 2002 Page 7

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