GCMS calibration table data, sample AE10517, May 22, 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052102\10517.D Vial: 19 Acq On : 22 May 2002 4:00 am Operator: Mclean Sample : re-extract Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 3 4-Chlorobuten-3-yne Concentration Rank 9 R.T. EstConc Area Relative to ISTD R.T.

3.91 1.61 ug/L 1005130 1,4-Dichlorobenzene-d4 9.90

Hit# of- 5 Tentative ID MW MolForm CAS# Qual

1 4-Chlorobuten-3-yne 86 C4H3C1 040589-38-6 /2 2 2 -Chloroethanol 80 C2H5C1O 000107-07-3/1 3 Methylene Chloride 84 CH2C12 000075-09-/ 1 4 Borane, trifluoro- 68 BF3 007637-07/2 1 Abundance Scan 141 (3.908 min): 10517.D (-140) (-) m/z 49.10 100.00% 49 88

5000- 36 82

41

4 •*.1+817}11**1*’11 187 • ’ i 58 3.60 3.80 4.00 4.20 Of ■»i “ “ i “ ■ ■ i1 ■1 ‘ i ■ ‘ “ i “ ■ ■ i' ■ TT m/z 51.10 71.09% miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12405:4-Chlorobuten-3-yne 51 86

5000 1**1**’*1***14***I’***I 3.60 3.80 4.00 4.20 m/z 88.00 68.55% 60

miz-> 01 5 j■ ‘* *। • *■mi■ • “ ।* ** • । “ i1 “ ■ i “ ■ ■ । 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Iagaaagai ......1111^..... Abundance #108328:2-Chloroethanol 31 1+***1**+I 3.60 3.80 4.00 4.20 5000 m/z 81.90 48.24% 27 44 49 L kW Of T ....................................... i""i T .33841 | .53 576063 Httpmtmmp 75 80 niz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12327: Methylene Chloride -— 99 49 3.60 3.80 4.00 4.20 84 m/z 36.10 45.51% 5000

14 18 24 2831 353841 88 0 TTUTIUTHTTTTTIWTTTNTT 152________ 70 1’0——0——m—3npunrTT - mtz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.60 3.80 4.00 4.20

10517.D 052202.M Wed May 22 11:48:07 2002 Page 6

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