GCMS sample AE12743 results, June 10 2002

NYC 9/11 Public Portal Document Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\060602\12761 .D Vial: 7 Acq On 6 Jun 2002 4:11 pm Operator: McLean Sample 6/3 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 6 4-Chlorobuten-3-yne Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. 3.89 0.83 ug/L 551941 1,4-dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual

l 4-Chlorobuten-3-yne 86 C4H3C1 040589-38-6 4/ 2 Propiolonitrile 51 C3HN 001070-71-9 /3 3 Ethanol, 2,2-dichloro- 114 C2H4C120 000598-38-9 2 4 1,1,2-Trifluoroethane 84 C2H3F3 000430-66/0 1 Abundance Scan 139 (3.896 min): 12761.D (-137) (-) m/z 51.10 100.00% 51

5000 88 42 ol ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ‘ ' I i * • * ■ । * * * ■ । * +l 3.60 3.80 4.00 4.20 m/z 47.05 60.93% m/z-> Abundance 10 20 30 40 50 60 70 80 #12405: 4-Chtorobuten-3-yne 51 90

86 100 110 120 AA/MMMo VMw, 5000 3.60 3.80 4.00 4.20 m/z 49.10 39.74% 60

miz-> 01 ■ । ■ ■ ■ ■ । ■ ■ ■ ■ i ■ ■' ■ । • ■ 10 20 30 40 50 mnl m......1 90 60 70 80 i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i • ■ 100 110 120 Abundance #12371: Propiolonitrile 51 3.60 3.80 4.00 4.20 5000 m/z 87.95 29.47%

n/z-> 0! -P 10 12 . 9 25 1 -32 pani 20 30 38

40 50 1 ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i • ' ■ ■ i ■ ■ ' ■ i ' ■ ■ ■ i ■ ■

60 70 80 90 100 110 120 /Mwau, Abundance #1082: Ethanol, 2,2-dichloro- 31 3.60 3,80 4.00 4.20 m/z 48.00 20.20%

5000

25 , 37 43 49 55 61 70 77 83 96 103 114 .Mn, 0 TIIHH1 ■ 1 ‘ 1 11 ■ 1 l ‘ ■ ■ ■ I ri ■ ■ । 1 ■ ■ । | ' i * । । 1 ■ 1 । । । 1 । > । 1 1 1 1 । । । m/z-> 10 20 30I 40 50 60 70 80 90 100 110 120 3.60 3.80 4.00 4.20

12761.D 060302.M Mon Jun 10 10:25:09 2002 Page 9

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