GCMS calibration table for TCLP extraction method

NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\052802\12287.D Vial: 6 Acq On : 28 May 2002 6:22 pm Operator: McLean Sample : 5/24 ad Inst : Instrumen Misc : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L * * * ****************************************************************** Peak Number 3 Propiolonitrile Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T.

3.76 0.98 ug/L 662052 1,4 -Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Propiolonitrile 51 C3HN 001070-71-9 3/ 2 Ethanol, 2,2-dichloro- 114 C2H4C120 000598-38-9/2 3 2-Butyne-1,4-diol, diformate 142 C6H604 036677-73-3 2 4 Butane, 2,2,3,3-tetranitro- 238 C4H6N4O8 020919-97-5 2 Abundance Scan 116 (3.761 min): 12287.D (-114) (-) m/z 48.10 100.00%

5000 37 48

84 w."M 340 3.60 3.80 4.00 4.20 O+ • l ■ ‘ ■ i ■ ■ • ■ i ■ 1II I' ■ ■■i11■ • । ■ 1 1 ■ i m/z 51.10 89.96% niz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #12371: Propiolonitrile 51

5000

"XsaAMWAMAWXC 340 3.60 3.80 4.00 4.20

miz-> Of - 12 . 10 20 18,432 34.., 30 40 5060 1 ■ ■ • । ■ ■ ■ ■ । ■ ■ ■ ■ । ■ ■ ■ ■ । • ■ ■ ■ ।

70 8090 100 110 120 130 Abundance #1082: Ethanol, 2,2-dichloro- 31

3.40 3.60 3.80 4.00 4.20 5000 m/z 37,10 54.44%

25 , I .1371 । 43 01 1 - ITT* ■ l 1Tt1a" 49 55 61 70 77. 83 96 103 114 l'i rl] . , . i’ll , . j . , 1 t'Cl'l’i i | l i i i | > i i I | I I I > | 1 i r I | I i

n/z-> 10 20 30I 40 50 60 70 80 90 100 110 120 130 Abundance #381:2-Butyne-1,4-diol, diformate ‘ ■ i ‘ ' i ■ ■ ■ ■ i ' 1 1 1 i 1 1 '' ' 1 1 29 39 340 3.60 3.80 4.00 4.20 m/z 36.10 49.42% 5000 51

68 pkdkpi"Wamou m/z—> 0 18 - i - ph 10 20 +— 30 40 50 60 .176 86 97 105 113 19/1/4 ■1 ■ i ■11 ■ i' ।1111''4111 1' i11' 1111 70 80 90 100 110 125 120 130 3.40 3.60 3.80 4.00 4.20

12287.D 052202.M Thu May 30 10:40:27 2002 Page 6

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