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GCMS Analysis Results, Sample AE08261, April 22, 2002

Machine-extracted title · confidence 100%

Initial analysis page for sample AE08261 showing surrogate recovery data and unknown compound screening.

NYC-WTC_000048287–000048308

Folder label: “GCMS X 4/9/02 A 4/17/02

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Scanned page image, NYC-WTC_000048299
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OCR status: ok · source: pdftotext

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\020417\08261.D Vial : 18 Acq On 17 Apr 2002 11:29 pm Operator: Nefliu Sample sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\041702SCAN.M (Chemstation Integrator) Title : 508-Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 4 Silane, tetramethyl- Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

5.97 0.43 ug/L 545035 1,4-Dichlorobenzene-d4 9.99 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Silane, tetramethyl- 88 C4H12Si 000075-76-3 43 2 Silane, tetramethyl- 88 C4H12Si 000075-76-3 43 3 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 1000186-02-3 28 4 N-Ethylformamide 73 C3H7NO 000627-45-2 9 Abundance Scan 492 (5.970 min) 08261 D (-487) (-) m/z 73.10 100.00% 73

5000 43 5.60 5.80 6.00 6 20 6 40 / 87 103 0 ' 1111' I ■'1' i11 '' ■ i1i1 ■ " i''' " i11 ■' i11" i1 ■ ■ ■ r " ■ r '1' r111 r11' r 1 m/z 43.05 26.13% n/z—> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #114826 Si’ane, tetramethyl- 73

5000 TIpmT 5 60 5.80 6.00 6 20 640 43 m/z 45.10 10.91% 2 15 2|9 ,1,1 53 65 88 0- mIPTTTPT Kp- " 11" " i " " i" " i " ■ ■ r " ■ r " ■ i Tp n/z- > 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #25349 Silane, tetramethy- 73 5 60 5.80 6.00 6.20 6.40 5000 m/z 41.10 10.53%

0- 2.. 15 ifr29315565 ..| .... .1 ' 111 M1111' 11 ,.. 88............................ " r " ' i'' " i1 "' i' " ' i " " I' "''T 1111" 111111111111111 n/z-> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #25344: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester ALAAAAAAMA,AAAAAH 73 560 5.80 6.00 6 20 6.40 m/z 71.10 5.95% 5000 43 27 55... .87... 113 131 174 0 111"11 ■"11" I‘r 11 ''i'111 ' I'" ’ I'" ' I' Tl/Z-> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 5.60 5.80 6.00 6.20 6.40

08261.D 041702SCAN.M Thu Apr 18 09:47:22 2002 Page 9

NYC-WTC_000048299

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NYC-WTC_000048299Source: NYC Law Department, mirrored locally

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