GCMS calibration table for method GCMS0412, April 2002

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Data File : C:\HPCHEM\1\DATA\APR1102\8016.D Vial: 22 Acq On : 12 Apr 2002 11:02 am Operator: Sample : gc/ms scan 4/4 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 7 5.alpha.-Pregnane-12,20-dione Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T.

40.46 0.83 ug/1 63959 Perylene-dl2 37.89

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 5.alpha.-Pregnane/12,20-dione 316 C21H3202 006022-48-6 11 2 3,5-Hexadien-2-onb, 5-methyl-6-(4-n 231 C13H13NO3 055191-23-6 9 3 Pyrimidine, 4-amino-2,6-bis (trifluo 231 C6H3F6N3 000717-61-3 9 4 2,5-Bis(2-chloro/1,1-dimethylethyl) 266 C10H16C12N2S 096594-29-5 9 Abundance Scan 3858 (40.463 min): 8016.D (-) m/z 231.10 100.00% 81 231 55 316 5000- 109 162

137 I J 207 255

140 60nW80 100i IA 120— 140T’Jt 160 180 200all220 240 260 PTTTT 281 386 40.20 40.40 40.60 40.80 1 m/ z 81.05 95.86% i"1 n/z-> 280 300 320 340 360 380 Abundance #45136: 5.alpha.-Pregnane-12,20-dione 43

5000 1 1 I 11 67 316 40.20 40.40 40.60 40.80 95 300 m/ Z 55.05 66.49% 124 149 ... ,l, 11,1,1,, 232 255 273 । ‘ i II1IIIIIIIIIIIIIIIIII■IIIIIII TTTTTUTUTTTHTTTTTTTTTTT 1177 m/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 Abundance #30119: 3,5-Hexadien-2-one, 5-methyl-6-(4-nitrophenyl)- 231 142 AA 1 A 1 ' ' ' I ' kr 40.20 40.40 40.60 40.80 109 5000 m/z 66.95 63.96

170

m/z-> ,..... I 188,21 ,rr1" i"111"1111 * " 11 *" 1’1’1’111011111133 214 4— 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 1' 11" ' I i" 11 r 1111 ‘ " 111 ■11 r 1

Abundance #30058: Pyrimidine, 4-amino-2,6-bis(trifluoromethyl)- 231 40.20 40.40 40.60 40.80 m/z 232.10 63.78%

5000 67 161 204 142 42 । 90 120 | 184 111" ■' i'1 I "'111 " TPT V 1 I | !! 1 . | !!!! | I !> I | ! I I I | ! I I | > I I , | | | | | | I I I I | | | 1 1 n-’ 1 > । ' ■ i 1 1 1 ■ i ■ 1 m/z—> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 40.20 40.40 40.60 40.80

8016.D GCMS0412.M Tue Apr 16 12:08:10 2002 Page 7

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