GCMS calibration table data, May 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\HPCHEM\1\DATA\MAY0302\9579.D Vial: 9 Acq On 3 May 2002 9:52 pm Operator: Sample GC/MS SCAN 4/24 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 8.16 11.60 ug/1 707505 1,4-Dichlorobenzene-d4 12.19

Hit# of 5) Tentative ID MW MolForm CAS# Qual

1 2-Pentanone, 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 64 2 CH2=CHG!H2C(O)OCH3 100 C5H802 003724-55-8 9 3 5-Hexen-2-one 98 C6H10O 000109-49-9 7 4 Acetone 58 C3H60 000067-64-1 7 Abundance / Scan 340 (8.157 min): 9579.D (-) m/z 43.05 100.00% 43

5000 59

101 7 80 8.00 8.20 8.40 8.60 38 I 53 i ■ 1 ' 1 i ■ 1 ' ' i 1 ' 1 ' I ' i■। । । r <h | i —i i 69 i [ i i i i । 83 i 'i i i | I 1TP“r‘ . | —I | r m/z 59.10 40.97% m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #64274: 2-Pentanone, 4-hydroxy-4-methyl- 43 _____ _____ _ _______ 5000 i i । i i I l l ) < T । i i i i । i

59 7.80 8.00 8.20 8.40 8.60 m/ Z 58.10 16.27% 27 101 - +4950— 60 83 m/z-> 10 20 -4 30 ..40 70 80 l ■ ■ ■ ■ । • ■ ■ ■ । ■1 ■ ■ ■ । ■ 90 100 1.11 110 Abundance #1448: CH2=CHCH2C(O)OCH3 43 IPP 7.80 8.00 8.20 8.40 8.60 5000 m/z 101.15 12.66

38— ■ । ■ ■ 56 ■■■ । ■ ■ ■ ■ । I 72 ■ ■ ■ । ■ ■ ■ ■ । 1 । । 100 । | -1 । r 1 । 1

m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #63205: 5-Hexen-2-one 43 7 80 8.00 8.20 8.40 8.60 m/ z 41.15 6.86% 5000-

27 55 15 50 .1 83 98 l 38 , ■ ■ ।1 1 1 ‘ । ■ TI— i T ।‘। । । | i n । | । i n । 11 i i । i i i I । i r—।—i—।—r m/z-> 10 20 30 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

9579.D GCMS0501.M Mon May 06 10:49:49 2002 Page 2

NYC-WTC_000046255