GCMS analysis results for sample AE10814, May 2002

NYC 9/11 Public Portal Document

• Data File : C:\MSDCHEM\1\DATA\051402\10814.D Vial : 24 Acq On : 15 May 2002 9:06 am Operator: Mclean Sample : 5/7 kb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 4 Phenanthrene-dlO Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

23.11 0.50 ug/L 642809 Phenanthranene-dl0 22.95

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene-dlO 188 C14D10 001517-22-2 74 2 Anthracene-dlO - 188 C14D10 001719-06-8 45 3 Cycloheptanone, 4-phenyl- 188 C13H160 067688-28-2 37 4 Pentacyclo[7.3.1.1. (4,12) . 0 (2,7) . . . 188 C14H20 1000215-61-8 36 Abundance Scan 3409 (23.109 min): 10814.D (-3402) (-) m/z 188.10 100.00% 188

5000 T I [ 1 — i— I — I | I ! I I ] I I I I r

80 94 22.80 23.00 23.20 23.40 43 54 66 0 I । r i i i । । i 1 i । > i ■ i ’I’i । । । । I i'i pTht I । ’ 11’ 146 158 11 r 1 " r 1111" " i " '' r 11' i11 ^T'1' m/ z 189.10 22.26% m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 188

5000 1 ■ i ■ ' T “‘ I ' 1 1 1 I ' ' 22.80 23.00 23.20 23.40 m/z 80.05 14.97% 80 94 160 30 42 52 66 0 11111111111 rri t I I I | I I I ! | I I I I | , 1 108118 132 rl I 1 11 11 I 11 1 pt 11 p i । t p । । rtfrrrj 146—44170179— m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79826: Anthracene-d 10- 188 ........ /............................. 1 i | i I I > | I । । a । i i i । | | i r i |

22.80 23.00 23.20 23.40 5000 m/z 93.95 11.52%

AA 80 94 1 60 ,| 17 30 42 52 0 , J 108 118 132 146 ,I 170179 J 0 I, । । । । । [ । । । Trrrt I’I ittor i p I I rpr II | I i i I | I I i i | 1 i i r । । i i 1 । i i i । ttrs rp i ti | i r lll*j‘i i i i [ ri Frft"r" Wr m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79739: Cycloheptanone, 4-phenyl- IPTI 188 22.80 23.00 23.20 23.40 117 m/z 184.05 10.77% 104 91 160 5000 131 170 27 39 51 65 78 145

0 --—44+4 TI’s Vnr ..... I I I I I I I 1.................... I I I I I I I 1 I I I I I I 1 I

m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 22.80 23.00 23.20 23.40

10814 .D 050102.M Thu May 16 14:16:42 2002 Page 7

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