GCMS analysis results for sample AE10610, May 10 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\l\DATA\050702\10610.D Vial: 13 Acq On 7 May 2002 10 : 55 pm Operator: Mclean Sample 5/3 kb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 4 2,5-Dihydrophosphole, 3-met.. Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T.

22.58 0.33 ug/L 396248 Phenanthranene-dl0 22.96

Hit# of 5 Tentative ID ■MW Mol Form CAS# Qual

1 2,5-Dihydrophosphole, 3-methyl-1... 192 C11H13OP 1000196-97-5 45 2 5H-Dibenzo[a,d]cycloheptene 192 C15H12 000256-81-5 45 3 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 42 4 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-5/42 Abundance Scan 3319 (22.580 min): 10610. D (-3309) (-) m/z 192.10 100.00% 192

5000

146 160 .......... 1..... /. I I I I I I I I I I I I “ I I I I I I I I I I

66 82 96 118 22.20 22.40 22.60 22.80 23.00 42 54 1 11 1 । । । 1 I' J11 1 । । । 1 । । । । । । 1 । । I I । q 1 1 I I I ' I I I I I I I I 1hi 1 1 til | 1 r I i | I I I 1 | H I 1 | I I I 1 | TP I'll l | III t | 111 | 1 m/z 191.10 20.50% /z—> 20 30 40 50 ।60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80965: 2,5-Dihydrophosphole, 3-methyl-1 -oxo-i -phenyl- 192 164

_______ / 5000 99 115 1 | > । 1 1 | । 1 I I | I k ! | f I f' I |" I

22.20 :22.40 22.60 22.80 23.00 47 77 177 m/z 146.10 17.34% 67 125 146 27 3?, 157 , i | r । i i । । i I ! I'i'r। rj r ri i । i i ri । i 84—4+44— 134,11155, TTIPTT m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80999:5H-Dibenzo[a,d]cycloheptene 192 -------- 22.20 22.40 22.60 22.80 23.00 177 m/ z 193.10 5000 14.48% 165 89

n/z-> 39 51 i । 1 1 1 1 | 1 1 1 11 >-i I |‘i

20 30 40 50 63 1 j 76 । | ,102 115 128 139 152 | i 1 । 1 'I' । li rfrrrlhj I I I 1 । i 1 l'i । 1 1 1 I । 1 r I 111 I ! 17 ! , [ All, | , II— i i

60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 + -rq-m

Abundance #81033: Phenanthrene, 9-methyl- 192 22.20 22.40 22.60 22.80 23.00 m/z 160.10 10.77% 5000

/z-> 29 39 51 63 74 83 96 al 115 126 139 152 165 j 176 . i 1 | I < 1 1 | 1 1 1 T | 1 1 > I | 1 1 I i | 1' 1 1 1 | r l‘l 1 |I i i‘l‘| I I I I [ I I I I J 1 1 1 1 ] 1 1 Ii j I I I I’ri I I rI’t I I I [I1! I I | I ll I | I I It

20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 u 22.20 22.40 22.60 22.80 23.00

10610.D 050102.M Thu May 09 09:15:20 2002 Page 7

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