GCMS reference analysis results for sample AE06337, May 3 2002

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Library Search Compound Report Data File C:\MSDCHEM\1\DATA\050102\6337.D Vial: 13 Acq On 1 May 2002 7:29 pm Operator: Mclean Sample re-ext 4/29 Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHQDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 6 5H-Dibenzo[a,d]cycloheptene Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 22.58 0.31 ug/L 323114 Phenanthranene-dl0 22.96 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 5H-Dibenzo[a,d]cycloheptene 192 C15H12 000256-81-5 45 2 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 42 3 5H-Tetrazole-5-thione, 1,4-dihyd... 192 C8H8N4S 1000142-22-5 42 4 lH-2-Indenone,2,4,5,6,7, 7a-hexah... 192 C13H20O 1000196-69-5 42 Abundance Scan 3319 (22.580 min): 6337.D (-3312) (-) m/z 192.10 100.00% 192

5000 ..... . 146 . KK 82। 96 160 । 22.20 22.40 22.60 22.80 23.00 42 66 j 118 . . ..... . ' i | I i । । | । । । । I i r i | I i । । | * i I i | i i If T Tt1 | i I i । i i i < । i i i I । i | j I । 1 ""i TT - m/z 191.10 16.87% /z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80999:5H-Dibenzo[a,d]cycloheptene 192

177 5000 7 11 । i-] ! 1 B [ >" 1 1 1 । l r y 1 22.20 22.40 22.60 22.80 23.00 89 165 m/z 146.10 16.44%| 39 51 76 63 I 115 128 139 152 11 n 47 l — 11 r " ''i" "1'"111,,n | , r | I1! rp I'l102 1 ' 1 ' ' “ I ' — r 1111 " 1 ''i' ! ! ! | 'I' I I ! | ! — ‘Id’ m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81033: Phenanthrene, 9-methyl- 192 ..................A............. / 22.20 22.40 22.60 22.80 23.00 5000 m/z 193.10 14.28%|

96 165 29 39 51 63 75 83 1 । i | 115 126 i 139 152 । 176 — TTITOIITNTTr TT I | i i i । i i i' । TTTr 1111111 113) i 119 i i r I i । i i i

m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80933: 5H-Tetrazole-5-thione, 1,4-dihydro-1-methyl-4-phenyl- —1 I ' ' 1 1 1 1 ' 1 1 1 1 1 r-i-| r 1 | 1 135 192 22.20 22.40 22.60 22.80 23.00 m/z 160.10 10.27% 77 5000 51 61 911 . 123 39 104 Im | I 11 II ri m ij 111H1r । i'I'i I li I | I I 149 163 —+1 ‘ J1'' ■ J' Vrr I I' | i > I I | | I | I | I I I | ! > I | - I f I I | । । । । | ' । । 1 i i I—I—|—i—rm—। | I

m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 23.00

6337.D 050102.M Thu May 02 12:22:25 2002 Page 9

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