GCMS blank analysis results for VOCs, May 9 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050702\0503LB.D Vial: 5 Acq On 7 May 2002 4:24 pm Operator: Mclean Sample 5/3 kb Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98.L ********************************************************************* Peak Number 5 Phenanthrene, 1-methyl- Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

22.58 0.29 ug/L 390053 Phenanthranene-dlO 22.96

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene, 1-methyl- 192 C15H12 000832-69-9 59 2 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 5 3 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 3 4 Phenanthrene, 3-methyl- 192 C15H12 000832-71- 53 Abundance Scan 3319 (22.580 min): 0503LB.D (-3310) (-) m/z 192.10 100.00% 192 A

5000

.................. । [ i । /.........../'j । it । ri r । । r~i । । । । । i ।

82 96 146 160 | 22.20 22.40 22.60 22.80 23.00 — ' 1111 p " 11 P ' 11 p ' ....... ..... F........... . 40 49 66 I 118 hI | 1 I Th | 1 1 1 1 | t 1 I 1 J 1 1 E i-| 1 I I 1 | I I I I I I I I I P I I I I I r I I I I I I I I I I I I I I I I I m/z 191.00 18.11% mlz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125856: Phenanthrene, 1-methyl- 192

5000 I ] । । । I | iiii । । । । । । i T r—

22.20 22.40 22.60 22.80 23.00 m/z 193.10 15.78% 27 39 51 63 82 96 II 115 126 139 152 cE 178 1 1 I Illi j I f I I I I I I pl I I I I I I I I I Thi rl'l । I I । । । । । । । । ri । । । f 1 t । । । । i‘] । । । । pt । । । । Pi t 1 । r 1 H । i r 1‛t T-p-r m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81033: Phenanthrene, 9-methyl- 192 ................ i | । । r i । i i i i pi i । । । i i fi ।—i—

22.20 22.40 22.60 22.80 23.00 5000 m/ z 146.10 14.60%

96 1 CE I 29 39 51 63 74 83 j 115 126 139 152 । 176 I 1 1 । 1 । 1 1 । i“i-ri |T i i 1 | I'l I r ] I ri i ।Ti ri 11 1'1 । । । । ri i । i TTTTT’ i i t I'l i i i । i1! I i ] I trprmth ’1 r 1 m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125842: Phenanthrene, 2-methyl- 192 22.20 22.40 22.60 22.80 23.00 m/ z 96.00 13.50%

5000

96 27 39 51 63 82 I 115 126 139 152 165 176 .........., TTTTT—nd00—01nTT i'l I i f] ' I ' ' | I I I I | I ' I I | I I I I | I I ’ I'l ' I I ! |'I I I I | i'l l T | I I I I | Tp-r "I I I I r I I I I I fl l 1 m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 23.00

0503LB.D 050102.M Thu May 09 09:21:08 2002 Page 8

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