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GCMS analysis results for unknown compounds, sample AE10201, May 2002

Machine-extracted title · confidence 95%

Laboratory report showing gas chromatography-mass spectrometry results for unidentified organic compounds in sample AE10201 on May 10, 2002.

NYC-WTC_000044959–000044977

Folder label: “GCMS X 4/30/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050802\10201.D Vial: 19 Acq On 9 May 2002 6:04 am Operator: Mclean Sample 4/30 eh ■ Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method. .C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library- : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 8 Phenanthrene, 9-methyl- Concentration Rank 5

R.T. EstConc . Area Relative to ISTD R.T. 22.58 0.34 ug/L 534742 Phenanthranene-dl0 22.96

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 59 2 Bitoscanate 192 C8H4N2S2 004044-65-9 53, 3 Thiophene, 2-[2-(3-thienyl)ethen... 192 C10H8S2 116854-09-2 50 4 6,2,5-Ethanylylidene-2H-qyclobut... 192 C11H12OS 019086-86-3/50 Abundance Scan 3318 (22.574 min): 10201 D (-3312) (-) m/z 192.05 100.00%l 192

5000 p 42 52 70 82 | 120 I . 160 H 22.20 22.40 22.60 22.80 23.00 o1 11 mn t 1111 11 111 11 i ri 111 f 11 ]‘l | > 111H i J11 I! rl i r| i H 11 ri 111111111 nr AWInIpt*mmtthhbnapenngunnI"uvjir m/z 191.10 18.38% m/z-> 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 Abundance #81033: Phenanthrene, 9-methyl- 192.

5000 l I I i I ' I I I I I I I 'I I T I I f I 1 I I

22.20 22.40 22.60 22.80 23.00 m/z 193.10 17.87% 96

/z-> 0 0-T 29 39 51 63 73 83 I TTUTETImm 115 126 139 152 " r *'11* I1 ‘11P'1" 11 r’1 |T If '11 io 20 30 40 50 60 70 80 90 100110120.130140150160170180190200 + 176 JI 165 TTHT+

Abundance #125827: Bitoscanate' 192 ■ i 1 1 22.20 22.40 22.60 22.80 23.00 5000 m/z 146.10 14.74% 134 50 63 75 90 160

/z-> o1 114 I14 0 " ■ 'i + 28 39 +lH+++ vlvr102rr 116n 1 117 10 20 30 40 50 60 70 80 90100110120130140150160170180190200 148 TTTTTI’’ " 11"11 TT" ■ ■ Abundance #81023: Thiophene, 2-[2-(3-thienyl)ethenyl]- 1 2 . .... 11 r 22.20 22.40 22.60 22.80 23.00 m/z 96.10 14.13% 147 5000 45 i 68 69 _ 96 ns I 27 50 1 I 82 1 I 134 . 158 0 ■■। ' 11""।"i '। ■ THTm 177 /z-> 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 22.20 22.40 22.60 22.80 23.00

10201.D 050102.M Thu May 09 13:37:08 2002 Page 12

NYC-WTC_000044975

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NYC-WTC_000044975Source: NYC Law Department, mirrored locally

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