GCMS analysis results, sample AE12321, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052902\12321.D Vial: 9 Acq On : 29 May 2002 4:36 pm Operator: McLean Sample : gc/ms scan 5/24 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan ‘5 Library : C: \DATABASE\NI ST9 8 . L ********************************************************************* Peak Number 11 Phenanthrene, 9-methyl- Concentration Rank 12 R.T. EstConc Area Relative to ISTD R.T.

22.54 0.27 ug/L 279815 Phenanthranene- dl 0 22.91

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 45) 2 Anthracene, 2-methyl- 192 C15H12 000613-12-7 42 3 3,4-Methylenedioxycinnamic acid 192 C1OH804 002373-80-0/40 4 Thiocyanic acid, 2-benzothiazoly. .. 192 C8H4N2S2 006011-99-0 40 Abundance Scan 3311 (22.533 min): 12321 .D (-3304) (-) m/z 192.10 100/00% 192

5000 - 42 52 66 82 % 120 146 160 22.20 22.40 22.60 22.80 0-T 1’21129711 Hhhttmptmmmmmp l m/z 191.00 17.28% n/z-> 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 Abundance #81033: Phenanthrene, 9-methyl- 19/2

5000 22.20 22.40 22.60 22.80 m/z 146.10 14.09% 29 39 51 63 74 83 d 115 126 139 152 165 176 I 0 11| 1111111111 ■ n 11 H । rj 1111 p n > । i’l 1111 rri rh rh i-R r| 11 u | m i (i ■ i ■ p i ip i n rp 1111 tmnahatTTp-> n/z-> 0 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200 Abundance #125844: Anthracene, 2-methyl- 1912 ..A...... 1. 22.20 22.40 22.60 22.80 5000 m/z 96.10 13.79%

96 165 63 74 1 115 139150 J 176 , 0 TPWWWIITOTTTTTTPTTTTmmTTTTTTTmTTTTTT Wn n/z-> 0 10 2030405060 70 80 90 100110120130140150160170180190200 Abundance #81021:3,4-Methylenedioxycinnamic acid 192 22.20 22.40 22.60 22.80 m/z 193.00 13.11% 5000

63 89 , 145 175

m/z-> 4 14 29 39 51 J 77 105 11 135 I, 163 0 optT i r" 11 rl’r ■ l’l’rr ‘r‘l| i r"I‘ 11 [‘ i’rr [, । ifpi 11 rdrt 11 mmphtam 0 10 20 30 40 50 60 70 80 90 10011012013014015016017018019020) u 1’41 ‘ 11 । । . i . . । 22.20 22.40 22.60 22.80 i’ । f

12321.D 052202.M Mon Jun 03 10:48:35 2002 Page 14

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