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GCMS calculation results for sample AE11602, May 2002

Machine-extracted title · confidence 90%

GCMS analysis report for sample AE11602 dated June 4, 2002, documenting unknown compounds and surrogate recovery.

NYC-WTC_000013921–000013942

Folder label: “GCMS X 5/24/02 A 5/28/02

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NYC 9/11 Public Portal Document Library search Compound Report Data File : C:\MSDCHEM\l\DATA\052802\11602.D Vial: 8 Acq On : 28 May 2002 8:00 pm Operator: McLean Sample : 5/24 ad re-ext Inst : Instrumen Mise • Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 12 Phenanthrene, 9-methyl- Concentration Rank 12 R.T. EstConc Area Relative to ISTD R.T. 22.53 0.26 ug/L 257768 Phenanthranene-dl0 22.91 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 53"), 2 Anthracene, 2-methyl- 192 C15H12 000613-12-7 42- J 3 1,3-Benzodioxole, 4-methoxy-6-(2... 192 C11H12O3 000607-91-0 42 4 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 42 Abundance Scan 3311 (22.533 min): 11602.D (-3300) (-) m/z 192.10 100.00% 192

5000

146 ....................... 9. 96 120 132 160 । 22.20 22.40 22.60 22.80)U‘ m/z-> 0- ..... 49.49 .... .............. mp aassam — T-p-r 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 2(X) m/z 191.00 17.73% Abundance #81033: Phenanthrene, 9-methyl- 192 A 5000 1ST 22.20 22.40 22.60 22.80 m/z 146.10 16.23% 96 29 39 51 63 74 83 115 126 139 152 0 nTuu1——3——0330——0——00‘—818fp7 111'111 ■■•'’I'''' i11' 'I'1111'1'1 165 176 1. I TTp-1 n/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125844: Anthracene, 2-methyl- 192 .S 22.20 22.40 22.60 22.80 5000 m/z 96.00 12.76%

96 165

n/z-> 0 -£3,,74.48.,1, —115—139,150.1744,,176... 11pn 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80895:1,3-Benzodioxole, 4-methoxy-6-(2-propeny!)- i ■ ■ ' ■ i ■ 1 ‘■ । ■ ■ i ■ ■ * • i ■ ■ 192 22.20 22.40 22.60 22.80 m/z 193.00 12.72% 5000 91 165 65 77 119 124 39 51 103 I 131 147

iz-> 0 -H— Ir — I Thm177 III,... T/t TI 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80

11602.D 052202.M Thu May 30 10:38:12 2002 Page 15

NYC-WTC_000013940

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NYC-WTC_000013940Source: NYC Law Department, mirrored locally

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