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GCMS results for sample AE07766, Apr 2002

Machine-extracted title · confidence 100%

Laboratory report documenting GCMS analysis of sample AE07766 including surrogate recovery and unknown compounds on April 18, 2002.

NYC-WTC_000046864–000046889

Folder label: “GCMS X 4/5/02 A 4/16/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\020415\07766.D Vial 28 Acq On : 16 Apr 2002 8:51 am Operator Nefliu Sample : sample Inst Instrumen Mise Multiplr 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\041202SCAN.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 5 Phenanthrene, 9-methyl- Concentration Rank 15 R.T. EstConc Area Relative to ISTD R.T. 22.64 0.21 ug/L 218106 Phenanthranene-dl0 23.02 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 50 2 2,5-Dihydrophosphole, 3-methyl-1... 192 C11H13OP 1000196-97-5 45 3 Bitoscanate 192 C8H4N2S2 004044-65-9 40 4 Thiophene, 2-[2-(3-thienyl)ethen... 192 C10H8S2 116854-09-2 40 Abundance Scan 3330 (22.645 min): 07766.D (-3325) (-) m/z 192.30 100.00% 192

5000

40 R7 96 146 160 70 82 | 118 — 2240 22 60 22 80 23.00 49 /z-> 0 ' i' " '11 — mmmp ' i ”'11 ■ ”11"1111 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 m/z 191.30 21.44% Abundance #81033: Phenanthrene, 9-methyl- 192 1

5000 2240 22.60 22.80 23 00 m/z 40.20 18.58% 96 29 39 51 63 75 83 | 115 126 139 152 165 176 II 0 «I • • ■' I • NTHTHTT TVTTTTWTNTITTTTTTTTTTHTT "I" Tl/Z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80965 2,5-Dihydrophosphole. 3-methyH-oxo-1-phenyl- 164 192

2240 22.60 22.80 23.00 5000 99 115 m/z 146.30 17.32% 47 77 177 67 125 1 34 146 /z--> 27 39 0 ....... ''I"' i'i'i'i ''i 457—L--441,771/1.74,54.,, Tmm 91 ii 107 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 TItt

Abundance #125828 Bitoscanate A ............. ( ■ r1 ' ■ • । ■ ■ ■ ■ । 192 2240 22 60 22.80 23.00 m/z 193.30 16.90% 5000

134 90 160

n/Z-> 4hr ... 0 11 ■ ■ ■ ■ i ■ 40 50 ........ 63 75 ----- 1.....Hu. ub TTTT 102 122 176 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 148 L 2240 22.60 22.80 1 i ' 1 23 00

07766.D 041202SCAN.M Tue Apr 16 13:42:06 2002 Page 8

NYC-WTC_000046876

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