GCMS calibration results for deuterated standards, May 2 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\1\DATA\0 5 010 2\CALIO.D Vial 3 Acq On 1 May 2002 11:20 am Operator Mclean Sample Inst Instrumen Mise Multiplr 1.00 MS Integration Params: EVENTS.E Quant Time: May 02 09:45:22 2002 Quant Results File: 050102.RES

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Last Update : Thu May 02 09:38:23 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.94 152 4444601 40.00 ug/L 0.00 10) Napthalene-d8 13.44 136 17806530 40.00 ug/L -0.01 17) Acenapthalene-dlO 18.57 164 9542480 40.00 ug/L 0.00 29) Phenanthranene-dlO 22.96 188 13945713 40.00 ug/L 0.00 37) Chrysene-dl2 30.82 240 10859325 40.00 ug/L -0.04 43) Perylene-dl2 34.72 264 7941685 40.00 ug/L -0.03

System Monitoring Compounds 2 7) TCMX 20.54 207 767474 10.19 ug/L -0.02 Spiked Amount 10.000 Recovery = 101.90%

Target Compounds Qvalue 2) n-nitros-dimethyl amine 3.87 74 822927 9.44 ug/L # 87 3) bis(2-Chloroethyl)ether 9.35 93 1899440 10.92 ug/L 87 4) 1,3-Dichlorobenzene 9.77 146 1943708 11.58 ug/L 97 5) 1,4-Dichlorobenzene 9.98 146 2144750 11.78 ug/L 98 6) 1,2-Dichlorobenzene 10.36 146 1852183 11.44 ug/1 98 7) 2,2‘oxybis(1-Chloropropane 10.78 45 2850372m 10.62 ug/L 8) N-nitroso-di-propylamine 11.13 70 1331481 10.79 ug/L 95 9) Hexachloroethane 11.26 117 745337 11.10 ug/L 94 11) Nitrobenzene 11.49 77 1803053 10.46 ug/L 94 12) Isophorone 12.20 82 3401291 10.96 ug/L 99 13) bis(2-Chloroethoxy) methan 12.95 93 2260087 11.00 ug/L 99 14) 1,2,4-Trichlorobenzene 13.30 180 1498924 11.49 ug/L 96 15) Napthalene 13.49 128 5571055 11.68 ug/L 98 16) Hexachlorobutadiene 13.93 225 706347 11.56 ug/L 99 18) 2-Chloronaphthalene 16.93 162 2774958 11.39 ug/L 98 19) Dimethylphthalate 18.01 163 3372082 10.80 ug/L 99 20) 2,6-Dinitrotoluene 18.12 165 486652 9.92 ug/L # 89 21) Acenapthylene 18.13 152 5104412 12.02 ug/L 97 22) Acenapthalene 18.66 153 3057858 11.77 ug/L 97 23) 2,4-Dinitrotoluene 19.27 165 484599 6.98 ug/L 96 24) Diethylphthalate 20.15 149 3061565 11.28 ug/L 98 25) 4-Chlorophenyl-phenylether 20.33 204 1625413 11.32 ug/L 98 26) Fluorene 20.20 166 3479958 11.72 ug/L 96 28) Azobenzene 20.78 77 4028308 11.24 ug/L 95 30) Nnitrosodiphenylamine 20.69 169 1968527 11.52 ug/L 94 31) 4-Bromophenyl-phenylether 21.76 248 808074 11.73 ug/L 95 32) Hexachlorobenzene 21.79 284 775602 11.76 ug/L 99 33) Phenanthrene 23.02 178 4958214 11.79 ug/L 98 34) Anthracene 23.17 178 5049741 11.73 ug/L 98 35) Di-n-butylphthalate 25.10 149 5202317 11.26 ug/L 99

(#) = qualifier out of range (m) = manual integration CAL10.D 050102.M Thu May 02 09:46:28 2002 Page 1

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