GCMS calibration results for Method 508, April 2002

NYC 9/11 Public Portal Document

A Quantitation Report (QT Reviewed) / • Data File C:\MSDCHEM\l\DATA\020408\0408C2.D Vial: 3 Acq On 8 Apr 2002 12:45 pm Operator: McLean Sample Inst Instrumen Mise 0 Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Apr 10 14:25:26 2002 Quant Results File: SCANAPR0902 .R

Quant Method : C:\MSDCHEM\1.. . \SCANAPR0902 .M (Chemstation Integrator) Title : Method 508 GC/MS Scan Last Update : Tue Apr 09 14:51:40 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN1

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 10.66 152 2408848 20.00 ug/1 0.00 10) Naphthalene-d8 15.77 136 9402199 20.00 ug/1 -0.01 17) Acenaphthene-diO 23.66 164 4892223 20.00 ug/1 0.00 31) Phenanthrene-diO 30.90 188 7711215 20.00 ug/1 0.00 39) Chrysene-dl2 39.10 240 6275911 20.00 ug/1 -0.02 45) Perylene-dl2 42.30 264 3079464 20.00 ug/1 0.00

System Monitoring Compounds 28) TCMX 26.53 207 57724 0.85 ug/1 -0.03 Spiked Amount 5.000 Recovery = 17.00% 38) 2,4-DDD 36.61 235 85309 0.88 ug/ml 0.00 Spiked Amount 5.000 Recovery = 17.60%

Target Compounds 6 1‘ Qvalue 2) N-nitrosodimethylamine 3.61 74 650999m 8.42 ug/1 3) bis(2-Chloroethyl)ether 9.96 93 1480376 10.32 ug/1 98 4) 1.3-Dichlorbenzene 10.41 146 1757730 10.13 ug/1 98 5) 1,4-Dichlorobenzene 10.72 146 1781312 10.17 ug/1 98 6) 1,2-Dichlorobenzene 11.24 146 1674144 10.15 ug/1 98 7) 2,2'oxybis(1-Chloropropane 12.04 45 2414713m 9.95 ug/1 8) N-Nitroso-di-n-propylamine 12.52 43 990385 10.26 ug/1 99 9) Hexachloroethane 12.52 119 598790 10.15 ug/1 97 11) Nitrobenzene 12.94 77 1647584 10.32 ug/1 97 12) Isophorone 14.03 82 2751656 10.15 ug/1 99 13) bis(2-Chloroethoxy) methan 15.26 93 1780201 10.21 ug/1 98 14) 1,2,4-Trichlorobenzene 15.62 180 1348141 9.89 ug/1 99 15) Naphthalene 15.85 128 4691481 10.36 ug/1 99 16) Hexachlorobutadiene 16.62 225 720906 9.69 ug/1 97 18) Hexachlorocyclopentadiene 19.80 237 283646 (6.59 ug/1 99 19) 2-Chloronaphthalene 21.14 162 2675251 9.97 ug/1 99 2 0) Acenaphthylene 22.95 152 3631403 9.68 ug/1 99 21) Dimethyl phthalate 23.04 163 2900924 9.90 ug/1 99 22) 2,6-Dinitrotoluene 23.15 77 141010 9.00 ug/1 # 87 23) Acenaphthene 23.79 153 2818064 10.19 ug/1 99 24) 2,4-Dinitrotoluene 24.92 165 473275 6.69) ug/1 96 25) Fluorene 26.20 166 2986150 9.84 ug/1 100 26) Diethyl phthalate 26.42 149 2842029 9.95 ug/1 98 27) 4-Chlorophenyl-phenylether 26.53 204 1389133 9.77 ug/1 96 29) N-Nitrosodiphenylamine 27.14 168 1190170 10.38 ug/1 97 30) Azobenzene 27.23 77 3416739 10.10 ug/1 98 32) Hexachlorobenzene 28.77 284 949676 9.38 ug/1 98 33) 4-Bromophenyl-phenylether 28.89 248 766735 9.24 ug/1 93

(#) = qualifier out of range (m) = manual integration 0408C2.D SCANAPR0902 .M Wed Apr 10 14:25:59 2002 Page 1

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