GCMS surrogate recovery data for sample AE07636, April 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\APR11O2\7636.D Vial: 12 Acq On : 12 Apr 2002 1:12 am Operator: Sample : gc/ms scan 4/3 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L Peak Number 2 Bis(2-ethylhexyl) phthalate Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 33.88 0.32 ug/1 36044 Chrysene-dl2 33.67 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Bis(2-ethylhexyl) phthalate 390 C24H3804 000117-81-7 86 2 1,2-Benzenedicarboxylic acid, 3-nit 211 C8H5NO6 000603-11-2 86 3 Di-n-octyl phthalate 390 C24H3804 000117-84-0 50 4 1,2-Benzenedicarboxylic acid, diiso 390 C24H3804 027554-26-3 43 Abundance Scan 3141 (33.878 min): 7636.D (-) m/z 149.00 100.00% 149

5000 57 167 41 71

mfe-> 20 40 L I 83 ill 80 lh 104 | 120 11 ′ I TTBI I ′ I I II ] L, 60 | 100 120 140 160 180 200 220 — 207 241 240 279 I ‘ i ' 1 1 1 i ■ ' 1 ' i 1 1 260 280 m/z 33.60 33.80 34.00 34.20 57.10 / 28.29% Abundance #53128: Bis(2-ethylhexyl) phthalate 149

5000 ■ ’ i 1 1 1 1 i ■ ’ 57 167 33.60 33.80 34.00 34.20 71 m/z 167.00 28.01% 83 113 279 I mlz—> 20 I ' ' TIT 1 40 60 4 80__ 100 —1324 120 140 160 > i ■ ■ ■ ■ i ■ ■ ■ ■

180 200 220 i ■ ■ ■ ■ i ■ ■

240 I ■ ■ । ■ • ■ ■ ।

260 280 ■

Abundance #25513:1,2-Benzenedicarboxylic acid, 3-nitro- 149 ' l ' ‘ 33.60 33.80 34.00 34.20 5000 m/z71.00 21.23%I 167 71 | 83 113 132 | i ' 1 1 1 i 1 ' 1 1 i ‘ TIt ]T TI I I ! I TI TT I I I I I TT I ] 1 I ] 1 ( I 1 id I I I I I I 1 I I I I I I TI I I I ] TT mfz-> 20 40. 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #74172: Di-n-octyl phthalate 11I 149 33.60 33.80 34.00 34.20 m/ z 41.05 17.49% 5000 57 71 167 27 83 113 279 1 — 132 I 1 1 1 1 1 ' .... 33.60 33.80 34.00 3420 m/z—> 20 40 60 80 100 120 140 160 180 200 220 240 260 280

7636.D GCMS0412.M Thu Apr 18 10:49:23 2002 Page 2

NYC-WTC_000040248