GCMS calibration results for Method 508, April 2002

NYC 9/11 Public Portal Document

I Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\1\DATA\020408\0408C5.D Vial: 6 Acq On 8 Apr 2002 3:33 pm Operator: McLean Sample Inst : Instrumen Mise 86.0 Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Apr 09 15:11:38 2002 Quant Results File: SCANAPR0902 .R

Quant Method : C:\MSDCHEM\1...\SCANAPR0902 .M (Chemstation Integrator) Title : Method 508 GC/MS Scan Last Update : Tue Apr 09 15:05:54 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN1

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 10.68 152 2732615 20.00 ug/1 0.00 10) Naphthalene-d8 15.80 136 10802141 20.00 ug/1 0.01 17) Acenaphthene-dlO 23.68 164 5615985 20.00 ug/1 0.00 31) Phenanthrene-dlO 30.91 188 9035549 20.00 ug/1 0.01 39) Chrysene-dl2 39.14 240 7975086 20.00 ug/1 0.02 45) Perylene-dl2 42.32 264 3837886 20.00 ug/1 0.01

System Monitoring Compounds 2 8) TCMX 26.58 207 575272 7.34 ug/1 0.03 Spiked Amount 5.000 Recovery = 146.80% 38) 2,4-DDD 36.61 235 101606 1.00 ug/ml 0.00 Spiked Amount 5.000 Recovery = 20.00%

Target Compounds lol i- Qvalue 2) N-nitrosodimethylamine 3.58 74 7603445 86.73 ug/1 99 3) bis(2-Chloroethyl)ether 10.00 93 12546713 77.10 ug/1 99 4) 1.3-Dichlorbenzene 10.44 146 15424828 78.33 ug/1 99 5) 1,4-Dichlorobenzene 10.75 146 15488622 77.97 ug/1 99 6) 1,2-Dichlorobenzene 11.28 146 14568172 77.87 ug/1 99 7) 2,2'oxybis(l-Chloropropane 12.07 45 10476907 (38.07ug/1 100 8) N-Nitroso-di-n-propylamine 12.60 43 8691784 79.39 ug/1 99 9) Hexachloroethane 12.54 119 5213828 77.94 ug/1 96 11) Nitrobenzene 13.00 77 14115169 76.99 ug/1 98 12) Isophorone 14.09 82 24269281 77.93 ug/1 98 13) bis(2-Chloroethoxy) methan 15.32 93 15632966 78.04 ug/1 99 14) 1,2,4-Trichlorobenzene 15.65 180 12425242 79.37 ug/1 100 15) Naphthalene 15.91 128 39604854 76.12 ug/1 100 16) Hexachlorobutadiene 16.65 225 7011231 82.03 ug/1 100 18) Hexachlorocyclopentadiene 19.81 237 5171803 —104.68 ug/1 99 19) 2-Chloronaphthalene 21.19 162 24303376 78.90 ug/1 99 20) Acenaphthylene 23.00 152 35628198 82.75 ug/1 100 21) Dimethyl phthalate 23.14 163 27003579 80.32 ug/1 100 22) 2,6-Dinitrotoluene 23.26 77 1520528 84.52 ug/1 # 90 23) Acenaphthene 23.86 153 24535113 77.31 ug/1 100 24) 2,4-Dinitrotoluene 25.02 165 7476301 92.04 ug/1 96 25) Fluorene 26.26 166 28087055 80.64 ug/1 100 26) Diethyl phthalate 26.49 149 26407449 80.56 ug/1 98 27) 4-Chlorophenyl-phenylether 26.58 204 13259373 81.20 ug/1 97 29) N-Nitrosodiphenylamine 27.22 168 10067313 76.47 ug/1 # 75 30) Azobenzene 27.28 77 30413003 78.33 ug/1 99 32) Hexachlorobenzene 28.86 284 10075124 84.90 ug/1 98 33) 4-Bromophenyl-phenylether 28.95 248 8350673 85.89 ug/1 96

(#) = qualifier out of range (m) = manual integration 0408C5.D SCANAPR0902 .M Tue Apr 09 15:12:01 2002 Page 1

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