GCMS calibration results for Method 508, April 2002

NYC 9/11 Public Portal Document

Quantitation. Report (QT Reviewed)

Data File C:\MSDCHEM\1\DATA\02 04 0 8\0 318REF2.D Vial: 10 Acq On 8 Apr 2002 7:15 pm Operator: McLean Sample 3/18 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Apr 09 15:08:47 2002 Quant Results File: SCANAPR0902.R

Quant Method : C:\MSDCHEM\1... \SCANAPR0902.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Last Update : Tue Apr 09 15:05:54 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN1

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 10.66 152 2346313 20.00 ug/1 -0.01 10) Naphthalene-d8 15.77 136 8872159 20.00 ug/1 -0.01 17) Acenaphthene-diO 23.66 164 4991357 20.00 ug/1 -0.01 31) Phenanthrene-diO 30.89 188 7871567 20.00 ug/1 -0.01 39) Chrysene-dl2 39.10 240 6104098 20.00 ug/1 -0.02 45) Perylene-dl2 42.30 264 3282736 20.00 ug/1 0.00

System Monitoring Compounds 28) TCMX 0.00 207 Od 0.00 ug/1 Spiked Amount 5.000 Recovery = 0.00% 38) 2,4-DDD 36.62 235 482479 5.48 ug/ml 0.00 Spiked Amount 5.000 Recovery 109.60%

Target Compounds S. / 3 Ol = Qvalue 2) N-nitrosodimethylamine 3.68 74 276879m 3.68 ug/1 3) bis(2-Chloroethyl)ether 9.94 93 1298214 9.29 ug/1 98 4) 1.3-Dichlorbenzene 10.40 146 886016 5.24 ug/1 98 5) 1,4-Dichlorobenzene 10.72 146 952960 5.59 ug/1 98 6) 1,2-Dichlorobenzene 11.23 146 984312 6.13 ug/1 98 7) 2,2'oxybis(1-Chloropropane 12.03 45 2130690m 9.02 ug/1 8) N-Nitroso-di-n-propylamine 12.51 43 912605 9.71 ug/1 99 9) Hexachloroethane 12.52 119 221418 3.85 ug/1 95 11) Nitrobenzene 12.92 77 1264261 8.40 ug/1 98 12) Isophorone 14.03 82 2489421 9.73 ug/1 100 13) bis(2-Chloroethoxy) methan 15.25 93 1597760 9.71 ug/1 99 14) 1,2,4-Trichlorobenzene 15.61 180 840274 6.54 ug/1 99 15) Naphthalene 15.85 128 3717122 8.70 ug/1 99 16) Hexachlorobutadiene 16.62 225 250007 3.56 ug/1 95 18) Hexachlorocyclopentadiene 19.80 237 35888 0.82 ug/1 83 19) 2-Chloronaphthalene 21.13 162 2190802 8.00 ug/1 99 20) Acenaphthylene 22.95 152 3388069 8.85 ug/1 100 21) Dimethyl phthalate 23.04 163 2894076 9.69 ug/1 99 22) 2,6-Dinitrotoluene 23.15 77 146834 9.18 ug/1 # 85 23) Acenaphthene 23.79 153 2502971 8.87 ug/1 100 24) 2,4-Dinitrotoluene 24.92 165 491405 6.81 ug/1 95 25) Fluorene 26.19 166 2778472 8.98 ug/1 99 26) Diethyl phthalate 26.41 149 2873284 9.86 ug/1 98 27) 4-Chlorophenyl-phenylether 26.53 204 1249899 8.61 ug/1 96 29) N-Nitrosodiphenylamine 27.13 168 973674 8.32 ug/1 97 30) Azobenzene 27.21 77 3005642 8.71 ug/1 98 32) Hexachlorobenzene 28.77 284 839053 8.12 ug/1 99 33) 4-Bromophenyl-phenylether 28.89 248 728988 8.61 ug/1 95

(#) = qualifier out of range (m) = manual integration 0318REF2.D SCANAPR0902.M Wed Apr 10 14:37:58 2002 Page 1

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