GCMS calibration table for TCLP analysis, Feb 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\l\DATA\FEB2102\REFB2.D Vial: 32 Acq On : 22 Feb 2002 9:42 pm Operator: Sample : gc/ms scan 2/21 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 27 11:15 2002 Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Thu Feb 21 16:13:52 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.33 152 333851 20.00 ug/1 -0.02 10) Naphthalene-d8 15.97 136 1294484 20.00 ug/1 -0.02 17) Acenaphthene-diO 21.29 164 682972 20.00 ug/1 -0.02 29) Phenanthrene-diO 25.74 188 975410 20.00 ug/1 -0.02 38) Chrysene-dl2 33.81 240 644385 20.00 ug/1 -0.03 44) Perylene-dl2 38.09 264 421794 20.00 ug/1 -0.03

System Monitoring Compounds 37) 2,4-DDD 30.81 235 54282 4.81 ug/mL 0.31 Spiked Amount 5.000 Recovery = 96.20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.95 74 62324 4.67 ug/1 # 73 3) bis(2-Chloroethyl)ether 11.72 93 146888 6.69 ug/1 95 4) 1,3-Dichlorobenzene 12.23 146 109127 4.18 ug/1 99 5) 1,4-Dichlorobenzene 12.38 146 114189 4.29 ug/1 97 6) 1,2-Dichlorobenzene 12.89 146 112770 4.46 ug/1 99 7) 2,2'-oxybis(1-Chloropropan 13.21 45 216510 6.52 ug/1 97 8) N-Nitroso-di-n-propylamine 13.60 70 105651 6.73 ug/1 # 86 9) Hexachloroethane 13.74 117 34185 3.21 ug/1 92 11) Nitrobenzene 14.02 77 134503 5.05 ug/1 95 12) 1sophorone 14.66 82 315742 7.02 ug/1 97 13) bis(2-Chloroethoxy)methane 15.34 93 172168 6.15 ug/1 97 14) 1,2,4-Trichlorobenzene 15.85 180 94632 4.27 ug/1 98 15) Naphthalene 16.03 128 371164 5.38 ug/1 99 16) Hexachlorobutadiene 16.57 225 33059 2.49 ug/1 98 18) Hexachlorocyclopentadiene 18.77 237 16095 1.65 ug/1 99 19) 2-Chloronaphthalene 19.54 162 218175 5.36 ug/1 98 20) Dimethylphthalate 20.63 163 303441 6.40 ug/1 100 21) 2,6-Dinitrotoluene 20.84 165 57850 5.38 ug/1 93 22) Acenaphthylene 20.81 152 358794 6.10 ug/1 99 23) Acenaphthene 21.38 153 242430 5.90 ug/1 99 24) 2,4-Dinitrotoluene 22.01 165 72654 5.34 ug/1 # 85 25) Diethylphthalate 22.76 149 309616 6.28 ug/1 97 26) 4-Chlorophenyl-phenylether 22.92 204 122555 5.78 ug/1 97 27) Fluorene 22.90 166 264702 5.90 ug/1 99 28) Azobenzen/ 1,2-Diphenylhyd 23.38 77 290973 5.61 ug/L # 91

(#) = qualifier out of range (m) = manual integration REFB2.D GCMS0208.M Wed Feb 27 11:18:24 2002 Page 1

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