GCMS reference analysis results for VOCs, Feb 27 2002

NYC 9/11 Public Portal Document

Quantitation rt (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\FEB2102aREFB.D Vial: 31 Acq On : 22 Feb 2002 8:43 pm Operator: Sample : gc/ms scan 2/21 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 25 8:28 2002 Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Thu Feb 21 16:13:52 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) l,4-Dichlorobenzene-d4 12.33 152 266364 20.00 ug/1 -0.02 10) Naphthalene-d8 15.97 136 1033461 20.00 ug/1 -0.03 17) Acenaphthene-diO 21.29 164 543015 20.00 ug/1 -0.03 29) Phenanthrene-diO 25.74 188 774439 20.00 ug/1 -0.03 38) Chrysene-dl2 33.81 240 534703 20.00 ug/1 -0.04 44) Perylene-dl2 38.09 264 363322 20.00 ug/1 -0.04

System Monitoring Compounds 37) 2,4-DDD 30.81 235 47958 5.35 ug/mL 0.32 Spiked Amount 5.000 Recovery = 107.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.95 74 52620 4.94 ug/1 # 74 3) bis(2-Chloroethyl)ether 11.72 93 125396 7.16 ug/1 95 4) 1,3-Dichlorobenzene 12.23 146 85755 4.12 ug/1 100 5) 1,4-Dichlorobenzene 12.37 146 91857 4.32 ug/1 99 6) 1,2-Dichlorobenzene 12.89 146 92939 4.61 ug/1 99 7) 2,2' -oxybis (1-Chloropropan 13.21 45 182060 6.87 ug/1 99 8) N-Nitroso-di-n-propylamine 13.59 70 89482 7.14 ug/1 # 86 9) Hexachloroethane 13.75 117 25028 2.94 ug/1 98 11) Nitrobenzene 14.01 77 112442 5.29 ug/1 94 12) 1sophorone 14.67 82 259008 7.21 ug/1 99 13) bis(2-Chloroethoxy)methane 15.34 93 147949 6.62 ug/1 97 14) 1,2,4-Trichlorobenzene 15.86 180 76880 4.35 ug/1 97 15) Naphthalene 16.03 128 313433 5.69 ug/1 99 16) Hexachlorobutadiene 16.58 225 22848 2.16 ug/1 97 18) Hexachlorocyclopentadiene 18.77 237 7507 0.97 ug/1 97 19) 2-Chloronaphthalene 19.54 162 183259 5.66 ug/1 97 20) bimethylphthalate 20.62 163 252023 6.68 ug/1 100 21) 2,6-Dinitrotoluene 20.84 165 46407 5.43 ug/1 91 2 2) Acenaphthylene 20.82 152 301855 6.45 ug/1 99 2 3) Acenaphthene 21.38 153 204383 6.25 ug/1 99 24) 2,4-Dinitrotoluene 22.01 165 58266 '5.38 ug/1 # 84 25) Diethylphthalate 22.76 149 252996 6.46 ug/1 98 26) 4-Chlorophenyl-phenylether 22.92 204 102663 6.09 ug/1 96 27) Fluorene 22.90 166 223885 6.28 ug/1 99 28) Azobenzen/ 1,2-Diphenylhyd 23.39 77 242392 5.88 ug/L # 89

(#) = qualifier out of range (m) = manual integration REFB.D GCMS0208.M Wed Feb 27 11:15:00 2002 Page 1

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