GCMS surrogate recovery data for PAHs, sample 3731, Mar 2002

NYC 9/11 Public Portal Document

Library Search Compound Report - Data File : C:\MSDCHEM\1\DATA\031202\3731.D Vial: 57 Acq On : 13 Mar 2002 2:46 am Operator: McLean Sample : SAMPLE 3731 2/19/02 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 3 1,2-Benzenedicarboxylic aci... Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 32.75 1.14 ug/L 435459 Perylene-d12 34.19 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 1,2-Benzenedicarboxylic acid.he•. 376 C23H3604 088216-58- 90 2 Di-n-octyl phthalate $$1,2 -Benz?. . 390 C24H3804 000117-84- 3 1,2-Benzenedicarboxylic acid, di... 362 C22H34O4 003648-21-3 80 4 1,2-Benzenedicarboxylic acid, di... 362 C22H34O4 003648-21-3 72 Abundance Scan 3272 (32.754 mln): 3731 D (-) m/z 149.00 100.00% 149

5000

57 II i ■ ■ • • i T TT 32.40 32.60 32.80 33.00 0- , 1483104 — 279 4- m/z 57.10 14.50% m/z-> 50 100 150 200 250 300 350 Abundance #318142:1,24 arbo heptyl octyl ester 149

5000 ----- —A - 32.40 32.60 32.80 33.00 m/z 150.00 10.08%

90 57 292376 m/z-> 0- 224,183104 50 176 150 ' 200 100 250 300 350 Abundance #326893: Di-n-octyl phthalate $$ 1,2-Benzenedicarboxylica... 149

IT — T 32.40 32.60 32.80 33.00 4 5000 m/z 55.10 9.67%

43 — 279 0- 14411714104 — 150 » I Ln ’1 I J f i l l l l I I I I I « miz-> Abundance 50 100 200 250 300 #308009: 1,2-Benzenedicarboxylic add, diheptyl ester 149 350 .... Lt 32.40 32.60 32.80 33.00 m/z71.10 6.20%

5000'

41 18. I J 76 104 176 203 . 265_________ 362 0 19 4.4 — * ■ *xd1dn/*1/**1//1/1.*1 111 • m/z—> 50 100 150 200 250 300 350 32.40 32.60 32*80 33.00

3731.D 5080302.M Fri Mar 15 14:27:01 2002 Page 5

NYC-WTC_000037601